METHOD FOR CONTINUOUS IMPLEMENTATION OF ELECTROCHEMICAL REACTION IN SUB AND supercritical fluids AND DEVICE FOR ITS PERFORMANCE

摘要

1. A method for the continuous implementation of an electrochemical reaction, including the supply of at least one stream of the initial reagent and electrochemical activation in the reaction zone of the electric discharge reactor, characterized in that first! A) feed the stream of the initial reagent with a supercritical fluid pressure, then! b) electrochemical activation of the specified flow of the initial reagent in the discharge zone (4) of the electric discharge reactor is carried out by an electric discharge with an anode current density of 0.1-200 kA / m2, preferably 1-20 kA / m2 at a subcritical fluid pressure, with a linear velocity of 0 , 1-500 m / s, preferably 1-100 m / s, and the period of time during which said electrochemical activation occurs with the formation of a plurality of vapor-gas bubbles of the cavitation mixture is substantially less than 60 s, preferably less than 10 s, then ! c) in the reaction zone (7) of the electric discharge reactor, the linear flow rate is sharply reduced to 0.000001-0.5 m / s, preferably to 0.0001-0.05 m / s, and at a supercritical fluid pressure, essentially in adiabatic conditions, the interaction of the specified cavitation mixture is carried out, and the period of time during which the specified interaction occurs, ensuring the collapse of the vapor-gas bubbles with the formation of the reaction mixture, is essentially less than 120 s, preferably less than 20 s, then! d) the specified flow of the reaction mixture is throttled through the reducing device (10), and at the same time the degree of opening of the reducing device (10) maintains the supercritical fluid pressure in the reaction zone (7) of the electric discharge p