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process for the production of a polymer based on conjugated dien, polymer based on conjugated dien and kautschukzusammensetzung

机译:于基于共轭二烯的聚合物的生产方法,基于共轭二烯的聚合物和kautschukzusammensetzung

摘要

A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass% or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.
机译:提供一种以低成本简单且廉价地生产分子量分布窄且顺式键含量高的共轭二烯聚合物的方法。该方法包括聚合步骤,其中具有98.5质量%以上的顺式-1,4-键含量和重均分子量(Mw)与数均分子之比(Mw / Mn)的共轭二烯聚合物。通过使用包含含稀土元素的化合物或含稀土元素的化合物的反应产物的催化剂组合物在共轭二烯化合物中进行聚合反应,可以得到2.5以下的通过凝胶渗透色谱法测定的重量(Mn)。 Lewis碱,铝氧烷和/或有机铝化合物以及含碘化合物。

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