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PHOTOPOLYMER FOR VOLUME HOLOGRAPHIC RECORDING AND ITS PRODUCTION PROCESS

机译:体积全息记录的光聚合物及其生产方法

摘要

The present invention refers to the manufacturing method of a holographic film and its development; the compositions of the films used in this invention are substantially solid and applied on a substrate in film or glass form; the photopolymerizable layer consists of a thickness of about 10 to 100 μm (microns), consisting of: a) 70% to 90% over the total weight of a thermoplastic “polymer”, b) 10% to 30% over the total weight of a preferably mono-functional photopolymerizable monomer reactive to light and, c) 1% to 10% per weight of an expansion agent that when heated at a minimum of 75° C. produces a gas in the unhardened or monomer polymerized areas of the hologram; furthermore, the composition contains a photoinitiator system sensitive to visible light, surfactants, plasticizers, etc.; photopolymerizable monomers used in this invention contains at least one part unsaturated ethylene with a boiling temperature equal or higher than 100° C.
机译:本发明涉及全息膜的制造方法及其发展。用于本发明的薄膜的组合物基本上是固体,并以薄膜或玻璃的形式涂在基材上。可光聚合层的厚度约为10到100μm(微米),包括:a)热塑性“聚合物”总重量的70%至90%,b)热塑性“聚合物”总重量的10%至30%优选的是对光具有反应性的优选单官能的可光聚合的单体,和c)重量为1%至10%的膨胀剂,该膨胀剂在最低75°C加热时会在全息图的未硬化或单体聚合区域产生气体;此外,该组合物含有对可见光敏感的光引发剂体系,表面活性剂,增塑剂等。用于本发明的光聚合单体包含至少一部分沸点等于或高于100℃的不饱和乙烯。

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