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GARNET-TYPE SOLID ELECTROLYTE, SECONDARY BATTERY CONTAINING GARNET-TYPE SOLID ELECTROLYTE, AND METHOD OF PRODUCING GARNET-TYPE SOLID ELECTROLYTE
GARNET-TYPE SOLID ELECTROLYTE, SECONDARY BATTERY CONTAINING GARNET-TYPE SOLID ELECTROLYTE, AND METHOD OF PRODUCING GARNET-TYPE SOLID ELECTROLYTE
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机译:石榴石型固体电解质,含石榴石型固体电解质的二次电池以及生产石榴石型固体电解质的方法
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摘要
A garnet-type solid electrolyte contains a crystal having (110) face, (1-10) face, (112) face, (1-12) face, and (11-2) face, the garnet-type solid electrolyte being Li7La3Zr2O12. A battery includes a solid electrolyte interposed between a positive and a negative electrode, the solid electrolyte being the garnet-type solid electrolyte. A method of producing a garnet-type solid electrolyte represented by a composition formula Li7La3Zr2O12 and has (110) face, (1-10) face, (112) face, (1-12) face, and (11-2) face as a crystal face, including a step of preparing a lithium-containing compound, a lanthanum-containing compound, and a zirconium-containing compound; a step of mixing these compounds such that a molar ratio among the elements satisfies Li:La:Zr=a:b:c (where a is from 120 to 160, b is from 1 to 5, and c is from 1 to 5); and a step of heating the mixture between 400 and 1,200° C.
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机译:石榴石型固体电解质包含具有(110)面,(1-10)面,(112)面,(1-12)面和(11-2)面的晶体,石榴石型固体电解质为Li。 7 Sub> La 3 Sub> Zr 2 Sub> O 12 Sub>。电池包括介于正极和负极之间的固体电解质,该固体电解质是石榴石型固体电解质。组成式为Li 7 Sub> La 3 Sub> Zr 2 Sub> O 12 Sub的石榴石型固体电解质的制造方法>具有(110)面,(1-10)面,(112)面,(1-12)面和(11-2)面作为结晶面,包括制备含锂化合物的步骤,含镧的化合物和含锆的化合物;混合这些化合物以使元素之间的摩尔比满足Li:La:Zr = a:b:c的步骤(其中a为120至160,b为1至5,c为1至5) ;以及在400至1200℃之间加热混合物的步骤。
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