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Formic acid dehydrogenation catalyst, hydrogen production method, deuterium gas or deuterium hydrogen production method

机译:甲酸脱氢催化剂,制氢方法,氘气或氘制氢方法

摘要

An object of the present invention is to provide a formic acid dehydrogenation catalyst capable of highly efficient production of hydrogen, deuterium gas, or deuterium free of carbon monoxide by dehydrogenation of formic acid. ), A dinuclear metal complex represented by the formula (1), a tautomer or stereoisomer thereof, or a salt thereof. In the above formula (1), M1 and M2 are transition metals, which may be the same or different, Q1 to Q6 are each independently carbon or nitrogen, and R1 to R6 are each Independently, a hydrogen atom, an alkyl group, a phenyl group, a nitro group, a halogen group, a sulfonic acid group, etc., and L1 and L2 are each independently an aromatic anion ligand or an aromatic ligand. And when it has a substituent, one or a plurality of the substituents may be present, and Y1 and Y2 are each independently an arbitrary ligand or absent, and m is a positive Integer, 0, or a negative integer. [Selection figure] None
机译:本发明的目的是提供一种甲酸脱氢催化剂,该甲酸脱氢催化剂能够通过甲酸的脱氢高效地生产氢气,氘气或不含一氧化碳的氘。 ),式(1)表示的双核金属络​​合物,其互变异构体或立体异构体或其盐。上式(1)中,M 1和M 2为相同或不同的过渡金属,Q 1〜Q 6分别独立地为碳或氮,R 1〜R 6分别独立地为氢原子,烷基, L 1和L 2分别独立地为苯基,硝基,卤素,磺酸基等,分别为芳香族阴离子配体或芳香族配体。并且,当其具有取代基时,可以存在一个或多个取代基,并且Y 1和Y 2各自独立地为任意配体或不存在,并且m为正整数,0或负整数。 [选择图]无

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