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DEHYDROGENATION CATALYST FOR FORMIC ACID, METHOD FOR PRODUCING HYDROGEN, AND METHOD FOR PRODUCING DEUTERIUM GAS OR DEUTERATED HYDROGEN
DEHYDROGENATION CATALYST FOR FORMIC ACID, METHOD FOR PRODUCING HYDROGEN, AND METHOD FOR PRODUCING DEUTERIUM GAS OR DEUTERATED HYDROGEN
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机译:甲酸的脱氢催化剂,氢的制备方法以及氘气或氘化氢的制备方法
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摘要
To provide a catalyst for dehydrogenation of formic acid which allows hydrogen, heavy hydrogen gas or heavy-hydrogenated hydrogen containing no carbon monoxide to be produced through dehydrogenation of formic acid in a highly efficient manner. A catalyst for dehydrogenation of formic acid, including: a multinuclear metal complex represented by the following Formula (1), a tautomer or stereoisomer thereof, or a salt thereof, where M 1 and M 2 denote transition metals and may be the same as or different from each other; Q 1 to Q 6 each independently denote carbon or nitrogen; R 1 to R 6 each independently denote, for example, a hydrogen atom, an alkyl group, a phenyl group, a nitro group, a halogen group, a sulfonate group (sulfo group); L 1 and L 2 each independently denote an aromatic anionic ligand or an aromatic ligand, and may be substituted by one or more substituents; Y 1 and Y 2 each independently denote any ligand or are absent; and m denotes a positive integer, 0, or a negative integer.
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