Templates of aflatoxin, Methods Of Synthesis of a compound of aflatoxin POLIMu00c9RICO intermediary template, molecularly imprinted polymer, method of preparation of molecularly imprinted molecularly imprinted Polymers, and Methods of secuestraciu00d3n of aflatoxin

摘要

Claim 1: a template of aflatoxin is a formula (1) wherein: ru00b9 cu2081u208bu2086 is selected from h, alkyl, alkyl and alkyl substituted cu2081u208bu2086 cu2081u208bu2086 halosustituido is selected; Ru00b2 Halo, cu2081u208bu2086 alkyl, alkyl substituted alkyl cu2081u208bu2086, a Cu2081u208bu2086 halosustituido, chu2082c and (OR) or CH (C (o) or) u2082; where r is selected from h,Cu2081u208bu2086 alkyl and substituted alkyl cu2081u208bu2086; and ru00b3 is selected from h, alkyl and alkoxy cu2081u208bu2086 cu2081u208bu2086 replaced. Claim 2: The staff of aflatoxin according to claim 1, characterized by an isolated Compound selected from the group consisting of the remains of a group of formula (2) and their combinations.Claim 6: A synthesis method of a template of aflatoxin, characterized by understanding: suspend an Ortho according to formula (3) in polyphosphoric acid and Heat until at least 25%; Cooling The reaction mixture to less than 25% aqueous solution and add a pa Ra get a template of aflatoxin with formula (4).Claim 15: a molecularly imprinted polymer comprising a crosslinked polymer of a Monomer, wherein the polymer has a Plurality of cavities, wherein at least one of the cavities were prepared using the template of aflatoxin which has the formula (1) Where ru00b9 is selected from h, alkyl cu2081u208bu2086,Cu2081u208bu2086 substituted alkyl and alkyl cu2081u208bu2086 halosustituido is selected; Ru00b2 Halo, cu2081u208bu2086 alkyl, alkyl substituted alkyl cu2081u208bu2086, a cu2081u208bu2086 halosustituido, chu2082c and (OR) or CH (C (o) or) u2082; where r is selected from h, alkyl and alkyl cu2081u208bu2086 cu2081u208bu2086 replaced; and Ru00b3 is selected from h, alkyl and alkoxy substituted cu2081u208bu2086 cu2081u208bu2086; or where ru00b9 along with Ru00b2 cycloalkyl cu2084u208bu2087 form a ring,A ring cu2084u208bu2087 cycloalkyl substituted cycloalkyl Ring Halo, a cu2084u208bu2087 replaced with cicloalcoxi cu2084u208bu2087 OXO, a ring, a ring cu2084u208bu2087 cycloalkyl substituted with Hydroxy substituted cycloalkyl ring and a cu2084u208bu2087 with carboxylic Group; and ru00b3 is selected from h, Coxi cu2081u208bu2086 cu2081u208bu2086 and alkyl substituted.Claim 22: a method of preparation of molecularly imprinted polymer, characterized by understanding the stages of: providing a template of aflatoxin which has the formula (1) where ru00b9 cu2081u208bu2086 is selected from h, alkyl, alkyl and substituted alkyl cu2081 cu2081u208bu2086 u208bu2086 halosustituido is selected; Ru00b2 Halo, cu2081u208bu2086 alkyl, alkyl substituted alkyl cu2081u208bu2086, a cu2081u208bu2086 halosustituido,Chu2082c and (OR) or CH (C (o) or) u2082; where r is selected from h, alkyl and substituted alkyl cu2081u208bu2086 cu2081u208bu2086; and ru00b3 is selected from h, alkyl and alkoxy substituted cu2081u208bu2086 cu2081u208bu2086; or where ru00b9 along with Ru00b2 form a ring cu2084u208bu2087 cycloalkyl ring, a cycloalkyl cu2084u208bu2087. Formed with Halo, a cycloalkyl substituted oxo cu2084u208bu2087 ring, a ring cicloalcoxi cu2084u208bu2087,A ring cu2084u208bu2087 cycloalkyl Hydroxy substituted cycloalkyl ring and with a cu2084u208bu2087 replaced with carboxylic Group; and ru00b3 is selected from h,Cu2081u208bu2086 alkyl and alkoxy substituted cu2081u208bu2086 aflatoxin; combine the template with at least one or more crosslinked monomer and polymerizing the monomer; and one or more crosslinked to form a favorable molecularly imprinted polymer; and removing the template of aflatoxin Molecularly imprinted polymer to the broker to form a molecularly imprinted polymer.A method of Reclaiming 33: sequestration of aflatoxin, characterized by understanding: provide a molecularly imprinted polymer having a Plurality of cavities, where at least one of the cavities is done using the template of aflatoxin which has the formula (1) ' And ru00b9 is selected from h, alkyl cu2081u208bu2086,Cu2081u208bu2086 substituted alkyl and alkyl cu2081u208bu2086 halosustituido is selected; Ru00b2 Halo, cu2081u208bu2086 alkyl, alkyl substituted alkyl cu2081u208bu2086, a cu2081u208bu2086 halosustituido, chu2082c and (OR) or CH (C (o) or) u2082; where r is selected from h, alkyl and alkyl cu2081u208bu2086 cu2081u208bu2086 replaced; and Ru00b3 is selected from h, alkyl and alkoxy substituted cu2081u208bu2086 cu2081u208bu2086; or where ru00b9 along with Ru00b2 cycloalkyl cu2084u208bu2087 form a ring,A ring cu2084u208bu2087 cycloalkyl substituted cycloalkyl Ring Halo, a cu2084u208bu2087 replaced with cicloalcoxi cu2084u208bu2087 OXO, a ring, a ring cu2084u208bu2087 cycloalkyl substituted with Hydroxy substituted cycloalkyl ring and a cu2084u208bu2087 with carboxylic Group; and ru00b3 is selected from h, Coxi cu2081u208bu2086 and alkyl substituted cu2081u208bu2086; provide a material,Where the material optionally contains an aflatoxin; and contacting the molecularly imprinted polymer with the material.