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Process for the preparation of compounds 2-hidroxifenilalquenilbenzotriazol and process for the preparation of siloxane-containing compounds function 2-hydroxyphenylbenzotriazole

机译:化合物2-hidroxifenilalquenil苯并三唑的制备方法和含硅氧烷官能的2-羟基苯基苯并三唑的化合物的制备方法

摘要

Process for preparing a compound of 2-hidroxifenilalquenilbenzotriazol, comprising at least the two following chemical steps: 1) etherification is carried out in a compound of 2-hydroxyphenyl benzotriazole in water and / or at least one organic solvent with a boiling point higher 200 ° C by reacting an alkenyl halide in the presence of at least one phase transfer agent and at least one base to obtain the corresponding compound alquenilfenilbenzotriazol 2 -O-; 2) a Claisen rearrangement of the compound 2-O-alquenilfenilbenzotriazol thus obtained is effected by heating the reaction mixture at a temperature above 170 ° C with at least one solvent organize a boiling point greater than 200 ° C.
机译:制备2-hidroxifenilalquenil苯并三唑的化合物的方法,其至少包括以下两个化学步骤:1)在水和/或至少一种沸点高于200°的有机溶剂中的2-羟基苯基苯并三唑的化合物中进行醚化C.在至少一种相转移剂和至少一种碱的存在下,使烯基卤化物反应,得到相应的化合物alquenilfenilbenzotriazol 2 -O-。 2)如此获得的化合物2-O-alilnilfenil苯并三唑的克莱森重排是通过将反应混合物在170°C以上的温度下与至少一种沸点大于200°C的溶剂加热而进行的。

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