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DIFLUORO BENZOTRIAZOLYL SOLAR CELL MATERIAL AND PREPARATION METHOD AND USE THEREOF

机译:二氟苯并三唑基太阳能电池材料及其制备方法和用途

摘要

The present invention relates to solar cells and discloses a difluoro benzotriazolyl solar cell material and preparation method and use thereof. The solar cell material is represented by formula (I), wherein both R 1 and R 2 are C 1 to C 20 alkyl, and n is an integer from 10 to 50. In the difluoro benzotriazolyl solar cell material, since the 1, 2, 3-benzotriazole solar cell material contains two fluorine atoms, the HOMO energy level is reduced by 0.11eV, while the fluorine-substituted 1, 2, 3-benzotriazole has two imido groups with electron-withdrawing ability; the fluorine-substituted 1, 2, 3-benzotriazole is a heterocyclic compound with strong electron-withdrawing ability, and an alkyl chain can be easily introduced to the N-position of the N-H bond of the benzotriazole. The functional group of the alkyl chain can improve the solar energy conversion efficiency, thus solving the low efficiency problem of solar cells made of the solar cell material.
机译:本发明涉及太阳能电池,公开了一种二氟苯并三唑基太阳能电池材料及其制备方法和用途。太阳能电池材料由式(I)表示,其中R 1和R 2均为C 1至C 20烷基,n为10至50的整数。在二氟苯并三唑基太阳能电池材料中,由于1,2,3-苯并三唑太阳能电池材料包含两个氟原子, HOMO能级降低了0.11eV,而氟取代的1、2、3-苯并三唑具有两个具有吸电子能力的亚氨基。氟取代的1、2、3、3-苯并三唑是具有强吸电子能力的杂环化合物,并且可以容易地将烷基链引入到苯并三唑的N-H键的N-位。烷基链的官能团可以提高太阳能转换效率,从而解决了由太阳能电池材料制成的太阳能电池效率低的问题。

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