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IR-OXOHYDROXIDES FOR ELECTROCHEMICAL OXIDATION OF WATER AND A METHOD FOR THE PREPARATION THEREOF

机译:用于水的电化学氧化的IR-羟基氧化物及其制备方法

摘要

The present invention relates to a catalytically active material for the electrochemical oxidation of water, wherein the catalytically active material comprises an amorphous Ir-oxohydroxide, wherein the catalytically active material has a specific surface area (SBET) of ≥50 m2.g-1; an electrode coated with the catalytically active material; a proton exchange membrane (PEM) based electrolyzer comprising the electrode; the use of the catalytically active material, the electrode or the electrolyzer the electrochemical oxidation of water; and a process for preparing the catalytically active material comprising the microwave- assisted thermal treatment of a basic solution of an Ir(III) or Ir(IV) complex.
机译:本发明涉及用于水的电化学氧化的催化活性材料,其中该催化活性材料包括无定形的Ir-羟基氧化氢氧化物,其中该催化活性材料的比表面积(S BET )为≥50m 2 .g -1 ;涂覆有催化活性材料的电极;基于质子交换膜(PEM)的电解器,其包括电极;使用催化活性材料,电极或电解槽对水进行电化学氧化;以及制备催化活性材料的方法,该方法包括对Ir(III)或Ir(IV)配合物的碱性溶液进行微波辅助热处理。

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