首页> 外国专利> VTE 123- SUBSTITUTED 123-TRIYLIDENETRISCYANOMETHANYLYLIDENE CYCLOPROPANES FOR VTE ELECTRONIC DEVICES AND SEMICONDUCTING MATERIALS USING THEM

VTE 123- SUBSTITUTED 123-TRIYLIDENETRISCYANOMETHANYLYLIDENE CYCLOPROPANES FOR VTE ELECTRONIC DEVICES AND SEMICONDUCTING MATERIALS USING THEM

机译:VTE 123-替代VTE电子设备和使用其的半导电材料的123-三亚乙基三氰基氰基亚芳基环丙烷

摘要

(i) loading the [3] -radialene p-dopant into an evaporation source, and (ii) evaporating the [3] -radialene p-dopant at an increased temperature and reduced pressure to produce an electrically doped semiconductor material comprising [3] -radialene p-dopant. Or [3] -radialene p-dopants, a method for producing an electronic device comprising a [3] -radialene compound, and a semiconductor material and a layer comprising the compound, / RTI [3] -radialene p-dopant has a structure according to the following formula (I): Wherein A 1 and A 2 are independently an aryl- or heteroaryl-substituted cyanomethylidene group, Aryl and / or heteroaryl in A 1 and A 2 are independently selected from the group consisting of 4-cyano-2,3,5,6-tetrafluorophenyl, 2,3,5,6-tetrafluoropyridin-4-yl, 4 (Trifluoromethyl) -3,5,6-trifluorophenyl, 2,5-bis (trifluoromethyl) -3, 5-trifluoromethyl-2,3,5,6-tetrafluorophenyl, 2,4- , 2,4,6-tris (trifluoromethyl) -1,3-diazin-5-yl, 3,4-dicyano-2,5,6-trifluorophenyl, 2-trifluoromethyl-3,5,6-trifluoropyridin-4-yl, 2,5,6-trifluoro-1, Diazin-4-yl and 3-trifluoromethyl-4-cyano-2,5,6-trifluorophenyl, At least one aryl or heteroaryl is selected from the group consisting of 2,3,5,6-tetrafluoropyridin-4-yl, 2,4-bis (trifluoromethyl) -3,5,6-trifluorophenyl, (Trifluoromethyl) -3,4,6-trifluorophenyl, 2,4,6-tris (trifluoromethyl) -1,3-diazin-5-yl, 3,4- Trifluorophenyl, 2-cyano-3,5,6-trifluoropyridin-4-yl, 2-trifluoromethyl-3,5,6-trifluoropyridin- 6-trifluoro-1,3-diazin-4-yl or 3-trifluoromethyl-4-cyano-2,5,6-trifluorophenyl, with the proviso that in both A 1 and A 2 , Tetrafluoropyridin-4-yl can not simultaneously be 2,3,5,6-tetrafluoropyridin-4-yl.
机译:(i)将[3-]-芳烃p-掺杂剂装载到蒸发源中,和(ii)在升高的温度和减压下蒸发[3-]-芳烃p-掺杂剂以制备包含[3]的电掺杂半导体材料。 -对苯二酚-p-掺杂剂。或[3]-芳烃p-掺杂剂,用于制造包含[3]-芳烃化合物,以及半导体材料和包含该化合物的层的电子器件的方法,[3]-芳烃-p掺杂剂具有根据下式(I)的结构:其中A 1 和A 2 独立地是A中的被芳基或杂芳基取代的氰基亚甲基,芳基和/或杂芳基 1 和A 2 独立选自4-氰基-2,3,5,6-四氟苯基,2,3,5,6-四氟吡啶- 4-基,4(三氟甲基)-3,5,6-三氟苯基,2,5-双(三氟甲基)-3,5-三氟甲基-2,3,5,6-四氟苯基,2,4-,2,4 ,6-三(三氟甲基)-1,3-二氮杂-5-基,3,4-二氰基-2,5,6-三氟苯基,2-三氟甲基-3,5,6-三氟吡啶-4-基,2, 5,6-三氟-1,二嗪-4-基和3-三氟甲基-4-氰基-2,5,6-三氟苯基,至少一种芳基或杂芳基选自2,3,5,6 -四氟Oropyridin-4-yl,2,4-bis(trifluoromethyl)-3,5,6-trifluorophenyl,(Trifluoromethyl)-3,4,6-trifluorophenyl,2,4,6-tris(trifluoromethyl)-1,3-二嗪5基,3,4-三氟苯基,2-氰基3,5,6-三氟吡啶-4-基,2-三氟甲基-3,5,6-三氟吡啶-6-三氟-1,3-二嗪- 4-基或3-三氟甲基-4-氰基-2,5,6-三氟苯基,条件是在A 1 和A 2 中,四氟吡啶-4- yl不能同时为2,3,5,6-四氟吡啶-4-基。

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