FIELD: chemistry.;SUBSTANCE: invention relates to organic chemistry, more specifically to a method of producing 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo[5,5,0,03,11,05,9]dodecane, used as highly efficient explosive. Disclosed method involves nitration of 2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazatetracyclo[5,5,0,03,11,05,9]dodecane with a sulphuric-nitric mixture and is characterised by that 2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazatetracyclo[5,5,0,03,11,05,9]dodecane is nitrated in crystalline form or in form of its aqueous-acetic solution of anhydrous sulphuric-nitric mixture containing free sulphuric anhydride. During nitration in crystalline form anhydrous sulphuric-nitric mixture containing free sulphuric anhydride in amount of 0.1–6.0 % is used, and during nitration in form of aqueous-acetic solution – anhydrous sulphuric-nitric mixture containing free sulphuric anhydride in amount of 6.0–15.0 %.;EFFECT: method enables to obtain an end product with high output and purity.;1 cl, 4 ex
展开▼
