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Active energy ray-curable composition, active energy ray-curable printing ink using same, and printed matter

机译:活性能量射线固化性组合物,使用其的活性能量射线固化性印刷油墨及印刷物

摘要

The present invention provides an active energy ray-curable composition exhibiting high curability and having excellent offset printability when used for a printing ink, an active energy ray-curable printing ink having both excellent curability and offset printability, and a printed matter using the same. An active energy ray-curable composition includes a urethane (meth)acrylate resin (A) and a polymerization initiator (B), wherein the urethane (meth)acrylate resin (A) is produced by using an aromatic polyisocyanate (a), a hydroxyl group-containing mono(meth)acrylate (b), and a polyol (c) as essential reaction raw materials so that the ratio [(b′)/(a′)] of the number of moles (b′) of hydroxyl groups contained in the hydroxyl group-containing mono(meth)acrylate (b) to the number of moles (a′) of isocyanate groups contained in the aromatic polyisocyanate (a) is within a range of 0.99 to 0.40, and the urethane (meth)acrylate resin (A) has a (meth)acryloyl group concentration within a range of 1.5 to 4.0 mmol/g.
机译:本发明提供了一种具有高固化性并且在用于印刷油墨时具有优异的胶版印刷性的活性能量射线固化性组合物,具有优异的固化性和胶版印刷性的活性能量射线固化性印刷油墨,以及使用该组合物的印刷物。一种活性能量射线可固化组合物,包括氨基甲酸酯(甲基)丙烯酸酯树脂(A)和聚合引发剂(B),其中氨基甲酸酯(甲基)丙烯酸酯树脂(A)通过使用芳族多异氰酸酯(a),羟基来制备。含基团的单(甲基)丙烯酸酯(b)和多元醇(c)作为基本反应原料,使得羟基的摩尔数(b')的比率[(b')/(a')]含羟基的单(甲基)丙烯酸酯(b)中所含的相对于芳族多异氰酸酯(a)中所含的异氰酸酯基的摩尔数(a')在0.99至0.40的范围内,并且氨基甲酸酯(甲基)丙烯酸酯树脂(A)的(甲基)丙烯酰基浓度为1.5〜4.0mmol / g。

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