The present invention relates to a novel sol-gel process for synthesizing a uniformly carbon-coated LiFePO 4 (LiFePO 4 / AS). The method comprises mixing a lithium source, phosphorus source and carbon source with a solution comprising Fe ions to form a gel; And providing a LiFeP0 4 (LiFePO 4 / AS), uniformly coating the carbon by baking the gel. According to the present invention, the phosphorus source is phosphonic acid.
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