A method for detecting a volatile analyte to class and sort cork stoppers depending on the concentration of the analyte, detection being preformed of concentrations in the order of ng/L (parts per trillion), in a concentrated gas applied to the cork stoppers in close containment. Cork stoppers are conveyed individually or groups to an incubation chamber; air/nitrogen is injected into the incubation chamber, the gas enriched with cork volatile compounds is entrained and carried to the concentration system containing a trap heated by desorption of entraining gas to a detection system recording a signal associated with presence of the analyte, the signal being used for classing the stopper/groups of stoppers; a software receives and compares the signal with a minimum limit, deciding to approve or reject the stopper. A system for implementing this method is described.
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