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Method for preparing furan-2,5-dicarboxylic acid (FDCA) from solid salt

机译:由固体盐制备呋喃-2,5-二羧酸的方法

摘要

The present invention relates to a process for preparing furan-2,5-dicarboxylic acid (FDCA) by converting furan-2,5-dicarboxylate salt (MFDC) to furan-2,5-dicarboxylic acid (FDCA) - Solid MFDC and inorganic acid (HY) are mixed to form a solution containing a solid FDCA in a concentration of 1 to 15% by weight in a solution of a salt of furan-2,5-dicarboxylate salt and an anion of inorganic acid (MY solution) Forming a reaction mixture, Separating the solid FDCA from the reaction mixture in a solid-liquid separation step, and - providing at least 40 vol% of the MY solution obtained from the solid-liquid separation step to the mixing step of MFDC and HY The method comprising: The step of providing a portion of the MY salt solution obtained from the solid-liquid separation step to the mixing step of MFDC and HY enables a stable and economical process to obtain the FDCA product with excellent quality and high yield.
机译:本发明涉及通过将呋喃-2,5-二羧酸盐(MFDC)转化为呋喃-2,5-二羧酸(FDCA)制备呋喃-2,5-二羧酸(FDCA)的方法-固体MFDC和无机混合酸(HY)以形成在呋喃2,5-二羧酸盐的盐和无机酸阴离子的溶液中含有浓度为1至15%重量百分比的固体FDCA的溶液(MY溶液)反应混合物,在固液分离步骤中从反应混合物中分离出固体FDCA,并且-将由固液分离步骤获得的MY溶液的至少40体积%提供给MFDC和HY的混合步骤。包括:将由固液分离步骤获得的MY盐溶液的一部分提供至MFDC和HY的混合步骤的步骤使得能够以稳定且经济的方法获得具有优异品质和高收率的FDCA产物。

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