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Film forming composition for semiconductor lithography process, silicon-containing film, and resist pattern forming method

机译:用于半导体光刻工艺的成膜组合物,含硅膜和抗蚀剂图案形成方法

摘要

An object of the present invention is to provide a film-forming composition for a semiconductor lithography process, a silicon-containing film, and a method of forming a resist pattern capable of forming a silicon-containing film having excellent resolution of a resist film, a collapse suppression of a resist pattern, and resistance to etching an oxygen-based gas. have. The present invention is a film-forming composition for a semiconductor lithography process containing a compound having a Si-H bond and an orthoester. The compound has, for example, at least one type of first structural unit selected from the group consisting of a structural unit represented by the following formula (1-1) and a structural unit represented by the following formula (1-2). In the following formulas (1-1) and (1-2), R 1 and R 2 are monovalent organic groups having 1 to 20 carbon atoms, hydroxy groups, or halogen atoms. R 3 is a substituted or unsubstituted divalent hydrocarbon group having 1 to 20 carbon atoms bonded to two Si atoms.
机译:本发明的目的是提供一种用于半导体光刻工艺的成膜组合物,含硅膜和形成抗蚀剂图案的方法,其能够形成具有优异抗蚀剂膜分辨率的含硅膜,抗蚀剂图案的塌陷抑制和抗蚀刻基于氧的气体的能力。有。本发明是用于半导体光刻工艺的成膜组合物,其包含具有Si-H键的化合物和原酸酯。该化合物具有例如选自下式(1-1)表示的结构单元和下式(1-2)表示的结构单元中的至少一种第一结构单元。在以下式(1-1)和(1-2)中,R 1 和R 2 是具有1至20个碳原子的一价有机基团,羟基或卤素原子。 R 3 是具有1至20个碳原子的两个Si原子相连的取代或未取代的二价烃基。

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