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Light trapping structures for photovoltaics using silicon nanowires and silicon micro-pyramids

机译:用于使用硅纳米线和硅微金字塔的光伏器件的光捕获结构

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摘要

The current photovoltaic industry is dominated by crystalline or poly-crystalline Si inuda planar pn-junction configuration. The use of silicon nanowire arrays (SiNWA) withinudthis industry has shown great promise due to its application as an anti-reflective layer,udas well as benefits in charge carrier extraction. In this work, we use a metal assistedudchemical etch process to fabricate SiNWAs onto a dense periodic array of pyramids thatudare formed using an alkaline etch masked with an oxide layer. The hybrid micro-nanoudstructure acts as an anti-reflective coating with experimental reflectivity below 1% overudthe visible and near-infrared spectral regions. This represents an improvement of up toud11 and 14 times compared to the pyramid array and SiNWAs on bulk, respectively. Inudaddition to the experimental work, we optically simulate the hybrid structure using theudcommercial Lumerical FDTD package. The results of the optical simulations support ourudexperimental work, illustrating a reduced reflectivity in the hybrid structure. The nanowireudarray increases the absorbed carrier density within the pyramid by providing a guidedudtransition of the refractive index along the light path from air into the silicon. Furthermore,udelectrical simulations which take into account surface and Auger recombination show anudeffi ciency increase for the hybrid structure of 56% over bulk, 11% over pyramid array andud8.5% over SiNWAs. Opto-electronic modelling was performed by establishing a tool udflow to integrate the eff ective optical simulator Lumerical FDTD with the excellent fabrication andudelectrical simulation capability of Sentaurus TCAD. Interfacing between the two packagesudis achieved through tool command language and Matlab, off ering fast and accurate electro-opticaludcharacteristics of nano-structured PV devices.
机译:当前的光伏产业以平面pn结配置中的晶体或多晶硅为主导。在该行业中使用硅纳米线阵列(SiNWA)已显示出巨大的前景,这是由于其作为抗反射层的应用以及在电荷载流子提取方面的优势。在这项工作中,我们使用金属辅助的 udchemical蚀刻工艺将SiNWAs制造到金字塔的密集周期性阵列上,该阵列经常使用被氧化物层掩盖的碱性蚀刻形成。杂化的微纳米结构充当抗反射涂层,在可见光和近红外光谱区域上的实验反射率低于1%。与金字塔阵列和SiNWA相比,这分别提高了 ud11和14倍。除了实验工作之外,我们还使用 Lumeralical FDTD软件包光学模拟了混合结构。光学模拟的结果支持了我们的实验工作,说明了混合结构中反射率的降低。纳米线 udarray通过提供沿从空气到硅的光路的折射率的导引 udtrans转换来增加金字塔内吸收的载流子密度。此外,考虑到表面和俄歇复合的电子仿真结果表明,混合结构的效率提高了56%(体积)以上,金字塔结构(11%)以上和SiNWAs(8.5%)以上。通过建立工具 udflow来进行光电建模,以将有效的光学模拟器Lumerical FDTD与Sentaurus TCAD的出色制造和电子仿真功能集成在一起。通过工具命令语言和Matlab实现的两个程序包之间的接口,提供了纳米结构的PV器件的快速,准确的电光附加特性。

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    Rahman Tasmiat;

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  • 年度 2016
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