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Biomimetic approach to anti-fouling surfaces

机译:防污表面的仿生方法

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摘要

Scale formation is recognized as one of the major problems affecting production in the oil and gas sector. There are many approaches to remove and prevent scaling with chemical inhibition, chemical scale removers and mechanical methods being the most prevalent ones. Recently the focus has shifted onto more environmentally friendly inhibitors that are less toxic to the environment, thus the development of green inhibitors. Another way forward is to turn to surface engineering - this is a very popular approach in the control of biofouling but only a few attempts have been made to use it for the purpose of scale inhibition. It is fair to say that there is a potential for more widespread study and exploitation of such systems. Biomimetics in surface engineering is receiving more attention as nature provides surfaces with a whole range of functionality. In the present work, microand nano-structured polymers surfaces with the self-cleaning Lotus and antireflective Moth-eye effects have been assessed as potential surfaces able to reduce mineral scale deposition. Calcium carbonate (CaCO3) was deposited onto them and their performance compared with reference stainless steel surfaces. In addition, the anti-scaling performance of three commercially available coatings – DLC, Tech 100 and Tech 23 was also investigated. The surfaces were tested in a rotating cylinder electrode (RCE) under different fluid hydrodynamic conditions i.e. both laminar to turbulent flow. Last but not least, micro-adhesion tests under water were conducted in an attempt to relate deposition tests to the adhesion properties of a single CaCO3 crystal against a surface as a measure of anti-scaling performance.
机译:结垢被认为是影响石油和天然气部门生产的主要问题之一。有许多通过化学抑制来去除和防止水垢的方法,化学除垢剂和机械方法是最普遍的方法。最近,焦点已转移到对环境毒性较小的更环保的抑制剂上,从而开发了绿色抑制剂。前进的另一种方法是转向表面工程-这是控制生物结垢的一种非常流行的方法,但是仅作了几次尝试将其用于抑制结垢。可以说,有可能对这类系统进行更广泛的研究和开发。由于大自然为表面提供了全部功能,因此仿生学在表面工程中受到越来越多的关注。在目前的工作中,具有自清洁荷花和防反射蛾眼效应的微米和纳米结构聚合物表面已被评估为能够减少矿物垢沉积的潜在表面。将碳酸钙(CaCO3)沉积在其上,并将其性能与参考不锈钢表面进行比较。此外,还研究了三种商用涂料DLC,Tech 100和Tech 23的防垢性能。在不同的流体流体动力学条件下,即层流至湍流,在旋转的圆柱电极(RCE)中测试表面。最后但并非最不重要的一点是,在水下进行了微附着力测试,试图将沉积测试与单个CaCO3晶体对表面的附着力相关联,以衡量防垢性能。

著录项

  • 作者

    Choo Wen Choo;

  • 作者单位
  • 年度 2010
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  • 原文格式 PDF
  • 正文语种 English
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