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中国涂料

中国涂料

China Coatings
本刊是由原国家科委批准出版、中国涂料工业协会主办，在国内涂料行业颇具影响的综合型科技期刊。1986年2月创刊，是以涂料、涂料原材料、涂料机械设备、涂料助剂、油墨、胶粘剂、防腐蚀、检测仪器等涂料相关行业为主要读者对象的中国涂料行业专业刊物。国内外公开发行。办刊宗旨：反映行业发展动态、透视产品最新走势、跟踪涂料高新技术、传递国外科技信息，融权威性、专业性、指导性为一体。
  • 发文量：7244
  • 被引量：667
  • H指数：0
  • 开始收录时间：1989(1)
  • CNKI综合因子：0.403
  • 维普期刊影响因子： 0.41
  • 万方期刊影响因子：0.38
  • 创刊时间：1986
  • 国内刊号/CN：11-3544/TQ
    国际刊号/ISSN：1006-2556
  • 发行周期：月刊
    邮发代号：82-810
  • 主管单位：中国石油和化学工业联合会
    主办单位：中国涂料工业协会
中国涂料-联系信息
  • 主编：樊森
  • 电话：010-62252368
  • 邮箱：chinacoatingnet@vip.163.com
  • 地址：北京市丰台区成寿寺158号办公楼四层西侧
  • 邮编：100079
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中国涂料 >2023年第8期

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  • 摘要：Through analyzing forming mechanism, accumulation position and gel volume, it was found that gel material mainly suspended in emulsion. Through comparing hydroxypropyl emulsion, pure acrylic emulsion and styrene acrylic emulsion, it was concluded that the molecular weight of the gel was not high. The main forming reason is the polymer and gel particle precipitation during aquous phase nucleation process. By pre-emulsiifcation process, the gel materials were eliminated.%通过分析羟丙乳液凝胶物质的产生时机、聚集位置和凝胶量，确定了凝胶物质的主体部分为悬浮于乳液中的凝胶物质。通过对比羟丙乳液、纯丙乳液和苯丙乳液的凝胶物质不同的物理化学特性，推断出羟丙乳液凝胶物质的分子量不大，并分析其产生的主要原因为水相成核过程聚合物和胶粒的析出。最终，通过采用预乳化工艺成功消除了羟丙乳液的凝胶物质。
  • 摘要：Timber characteristics for solid wood furniture were introduced. The water content of wood should be suitable controlled. Clear coatings instead of solid colour coatings were suitable for the coating of solid wood furniture to match the natural texture of the wood. The coating process and formula design for solid wood furniture were discussed.%介绍了实木家具用木材的特点，指出要合理控制木材的含水率。实木家具为了表现木材的天然质感适合做清漆涂装，不适合做实色涂装；提出了实木家具透明涂装的推荐工艺，并简单介绍了每步工艺需要的产品的配方设计。
  • 摘要：实验应用Matlab 2013b建立了用于冷喷涂Cu-Cu2O涂层在多环境变量海水中的铜渗出率预测的BP人工神经网络系统。网络采用5-28-1三层网络结构，隐层传递函数为对数S型函数(logsig)，输出层传递函数为线性函数(purelin)，训练函数采用trainlm函数，训练误差目标设置为1×10-7，训练前对网络的权值和阈值进行零初始化。实验结果表明该神经网络具有很好的预测能力和泛化能力，能够有效地预测冷喷涂C u-C u2O涂层在多环境变量海水中的铜渗出率，预测误差在10%以内。%BP artiifcial neural network system used to predict copper leaching rate of cold spray Cu-Cu2O coatings in multivariate marine environment was established by Matlab 2013b. The network was a three-tier structure of 5-28-1. Hidden layer transfer function was S-shaped logarithmic function (logsig) and the transfer function of the output layer was a linear function (purelin). The training function token trainlm function and training error target was set to 1×10-7. Before training, the weights and threshold of the network was initialized to zero. Experimental results indicated that the neural network had good predictive ability and generalization ability. It can effectively predict the copper leaching rate of cold spray Cu-Cu2O coating in multivariate seawater environment and the prediction error is within 10%.
  • 摘要：针对国内外汽车用高装饰涂层的专利申请情况进行了客观的分析，为国内相应的汽车用高装饰涂料的生产商或研发机构提供专利技术方面的信息，以期找到国内外差距，为国内申请人的研发和专利申请提供一定的借鉴作用。%Through objective analysis of national and international patent application in the ifeld of automotive high decoration coating technology, patent information was provided for the domestic manufacturer or the correlated research institute to ifnd the gap between the national and the international.
  • 摘要：简述了木器用水性洒点漆的制备过程及应用方法，探讨了该产品的相关性能指标、原料的影响因素、改善方案及其未来发展方向。%The preparation and application of waterborne sprinkle wood paint was discussed. The related technical properties, inlfuences of raw materials and improvement plan were studied. The trend was forecasted.
  • 摘要：With the modiifed polyester (PE001) and polycarbonate diol (T5652) as soft chain segment, isophorone diisocyanate (IPDI) as hard chain segment,α,ω-Polypropylenglycol-diamine-sulfopropylate, Na-salt (Poly-EPS) and dimethylol propionic acid (DMPA) as hydrophilic chain extender, 1,6-hexanediol (HDO) or hydrogenated bisphenol A (HBPA) as small molecular chain extender, a sulfonate/carboxylate waterborne polyurethane with high solid was prepared. The inlfuence of polyester type and different ratio with content of sulfonate and carboxylate on the performance of resin iflm was studied. In order to improve the stability and bring in structure of cyclohexyl, the hydrogenated bisphenol as small molecular chain extender has been introduced. FT-IR、TGA、TEM was used to characterize the latex particles. The results showed that with the low viscosity high solid and well dispersed waterborne polyurethane was synthesized. The resin showed good stability and excellent iflm comprehensive performance when the ratio PE001∶T5652 was 5∶1, the total content of hydrophilic extender was 4% (the content of DMPA was 2%).%以改性聚酯(PE001)、聚碳酸酯二醇(T5652)为软段，异佛尔酮二异氰酸酯(IPDI)为硬段，以α,ω-聚丙二醇二胺-磺丙基钠盐(Poly-EPS)和二羟甲基丙酸(DMPA)为亲水扩链剂，以氢化双酚A(HBPA)或己二醇(HDO)为小分子二元醇制备了高固含量磺酸/羧酸盐型水性聚氨酯树脂。研究了聚酯种类的不同以及磺酸和羧酸含量比例不同时对树脂胶膜的性能影响，原料中小分子二元醇为氢化双酚A，引入环己烷结构，提高稳定性。采用傅里叶红外光谱(FTIR)、热重分析(TGA)、透射电镜(TEM)对其结构进行表征。结果表明；所制备的水性聚氨酯树脂黏度小、固含量高，分散均匀；当混合聚酯(PE001∶T5652)比例为5∶1，总亲水扩链剂为4%(其中DMPA含量为2%左右)时，树脂稳定性良好，胶膜综合性能优异。
  • 摘要：Intelligent coating test line of Taiho could deal with the three-dimensional drying. It was divided into intelligent microwave drying oven, nano electrolytic drying oven, IR field effect drying oven and UV curing drying oven. The drying conditions of one component and two component waterborne wood coatings for optimization of physical properties were researched.%智能化涂装测试线可全方位处理立体干燥问题，其主要包括智能微波干燥炉、纳米电解干燥炉、IR场效应干燥炉及光固化干燥炉。重点探讨了单组分与双组分的水性木器涂料在何种的干燥条件下可以达到最佳的干燥效率并达到较好的物理性质。
  • 摘要：金属填料一般具有较低的发射率和较高的反射率。同种金属颗粒由于形态、粒径不同会影响其发射率；同种形态同等粒径下不同的添加量也会影响其发射率。讨论了选用金属填料时，其粒子形态、粒径大小、添加量及取向排布等因素对发射率的影响。%Usually, the emissivity of metal pigments is lower, the relfectivity of metal pigments is higher. The same metal particles inlfuence the emissivity because of its morphology and particle size and the dosage also inlfuences the emissivity. The inlfuence factors of its morphology, particle size, dosage and orientation permutation distribution were discussed.
  • 摘要：2016年5月12-15日,由中国石油和化学工业联合会、中国就业培训技术指导中心以及中国涂料工业协会联合主办的国家一级二类赛事——＂第八届全国石油和化学工业行业职业技能竞赛、全国水性木器涂料涂装工职业技能竞赛＂总决赛顺利在江苏昆山召开。
  • 摘要：从辐射光源、辐照能量、走带速度、湿膜厚度、光引发剂种类及光引发剂用量以及树脂本身的影响等角度出发，对水性UV木器清漆体系涂膜性能的影响因素作了探讨。%The inlfuencing factors including radiation light sources, radiation energy, line speed, wet iflm thickness, photoinitiator and resins were studied for waterborne UV wood clearcoat.
  • 摘要：JG/T481—2015《低挥发性有机化合物(VOC)水性内墙涂覆材料》标准新近发布，将新标准与GB18582—2008和HJ2537—2014进行了对比，并通过对乳液、成膜助剂和防冻剂的筛选复配，研制出满足新标准JG/T481—2015要求的内墙水性涂料。%JG/T 481—2015Low VOC Waterborne Interior Wall Coating Materials was released. It was compared with GB 18582—2008 and HJ 2537—2014. Through selection of emulsion, additive and anti-icing agents, new interior wall waterborne coatings were prepared to satisfy the new standard JG/T 481—2015.
  • 摘要：A self-crosslinking acrylate emulsion with core-shell structure is synthesized through semi-continuous emulsion polymerization method. It is conifrmed that the emulsion has better performance with 50%solid content, 315 mPa · s viscosity and 93 nm grain size when dosages of crosslinking monomer MAA, DAAM and organosilicone monomer are separately 3%wt, 3%wt and 1%wt of total monomer dosage. The emulsion can be used to prepare waterborne wood primer and top coatings with low content VOC and quick-drying feature. The iflm covers performances of fullness, rubbing property, transparency and so on. It can be applied conveniently and only one primer and one surface coats can obtain favorable construction performance, which shortens the construction time.%采用半连续乳液聚合法合成了一种自交联型具有核壳结构的丙烯酸酯乳液，确定了交联单体MAA、DAAM和有机硅单体用量分别为单体总量3%、3%和1%（均为质量分数）时，乳液的综合性能更好，其固含量为50%，黏度为315 mPa · s，粒径为93 nm。该乳液可用于配制水性木器漆底漆和面漆，VOC含量低，快干，涂膜具有较好的丰满度、打磨性和透明度等性能，施工方便，喷涂一底一面即可获得很好的施工性能，缩短施工时间。
  • 摘要：针对国内外汽车用高装饰涂层的专利申请情况进行了客观的分析，为国内相应的汽车用高装饰涂料的生产商或研发机构提供专利技术方面的信息，以期找到国内外差距，为国内申请人的研发和专利申请提供一定的借鉴作用。%Through objective analysis of national and international patent application in the ifeld of automotive high decoration coating technology, patent information was provided for the domestic manufacturer or the correlated research institute to ifnd the gap between the national and the international.
  • 摘要：Talent cultivation before and after reform and opening up was introduced in China. The importance to cultivate coatings talents was highlighted and problems were analyzed. Cultivation experience, concept and model were introduced. China Coatings Industry University was introduced as well.%叙述了改革开放前后涂料人才培养方式和创办涂料专业的曲折历程，及涂料专业人才培养的重要性和面临的问题；对在创办涂料工程专业过程中积累的人才培养经验、理念和将要试行的新培养模式作了简介，最后介绍了足以载入史册的行业大事——中国涂料工业大学揭牌成立的盛况。
  • 摘要：以IPDI为硬段，PTMEG1000、PPG1000为软段，采用DMPA、BDO为小分子扩链剂，通过调整软硬段比例，制备出水性聚氨酯树脂。该树脂作为水性木器涂料的成膜树脂，除了具备良好的力学强度、耐化学品性能，同时具有优秀的成膜性能，可以有效降低成膜助剂的使用量。%With IPDI as hard segment, PTMEG1000 and PPG1000 as soft segment, and DMPA and BDO as micromolecule chain extender, a waterborne polyurethane resin is formulated by adjusting the proportion of the soft segment and the hard segment. As a iflm-forming resin for waterborne wood coatings, the resin not only has favorable mechanical strength and chemical resistance, but also offers outstanding iflm-forming properties and can effectively reduce the consumption of iflm-forming additive.
  • 摘要：主要介绍了汽车涂装中阴极电泳涂膜二次流痕的产生机理及常用的解决思路、方案实施、效果验证过程。%This paper mainly introduces the production mechanism, common solution, scheme implementation and effect veriifcation process of the secondary lfow marks in CED coatings for automotive coatings.
  • 摘要：综述了近年来我国涂料行业环保相关标准体系指标的进步；并结合溶剂型涂料水性化过程中存在的难点问题，分类概括了不同类型溶剂型涂料水性化过程中的主要技术进步。依据国家建筑材料测试中心近几年的检测数据，对水性内墙涂料和溶剂型木器涂料的环保性能变化趋势进行了分析总结。%Related environmental standards in coatings were summarized. Some critical problems in waterborne coatings were sated and the main technical progress of solventborne coatings were introduced. According to the test data from National Building Materials Test and Certiifcation Center, the trend of waterborne interior coatings and solventborne wood coatings was analyzed.
  • 摘要：介绍了通过乳液筛选、助剂搭配制备满足实木透气门窗性能要求的水性白面漆以及主要性能检测方法。%Waterborne white topcoats that can satisfy performance requirements for solid wood ventilate doors and windows and main performance test methods are introduced through emulsion screening and additives collocation and formulation.
  • 摘要：Expansion ifre proof and thermal insulation coatings was developed based on the two-component solvent free epoxy ifre proof coatings. Screen the thermal insulation ifller and increase the heat insulation effect under the normal temperature in the prerequisite of coating ifre proof performance, enabling the coating with the function of thermal insulation, heat preservation and ifre proof. Thermal conductivity at normal temperature, smoking release, heat release and ifre performance under simulated ifre, and ifre proof performance of cellulose ifre simulation beam and thermal insulation of hydrocarbon ifre were tested for sample coatings. Experimental data showed that, if hollow microspheres are adopted as the ifller of expansion ifre proof and thermal insulation coatings, it has the lowest thermal conductivity at normal temperature, lowest smoke and heat release performance;the expansion carbon layer is uniform and compacted and there is no decline in the ifre proof performance compared with other ifllers. After tests, the new products were proved to comply with the standard GB 14907-2002 regarding the outdoor thin stell structure ifre proof coatings.%在双组分无溶剂环氧防火涂料的基础上，研制了一种膨胀型隔热防火涂料。筛选隔热填料，在保证涂层防火性能的前提下，增加其在常温下的热量隔绝效果，使涂层具隔热、保温、防火的功能。对样品进行常温导热系数、模拟火灾条件下的烟释放性能、热释放性能、纤维素火模拟钢梁的防火性能、烃类火隔热性能的测试。实验数据表明，选用空心微珠作为膨胀型隔热防火涂料的填料，其常温下导热系数最小，烟释放性能和热释放性能最低，膨胀碳层均匀致密，防火性能与其他填料相比无下降。最终研制的膨胀型隔热防火涂料，经全项性能测试，满足G B 14907—2002中室外薄型钢结构防火涂料的各项指标要求。
  • 摘要：针对2款适用于环氧涂料中的聚酰胺改性流变助剂产品(聚酰胺蜡M和聚酰胺蜡P )，探讨操作活化温度及时间，了解其黏度与抗流挂等性能达到最佳的条件，以供涂料客户在使用该类产品时进行流程优化作参考。%Two classic polyamide rheological additives (Polyamide Wax M and Polyamide Wax P) were researched through varying activation temperatures and times to see the viscosity and sagging property. Optimal conditions for epoxy paint were investigated for providing references for customers and manufacturers.
  • 摘要：就碳酸二甲酯(DMC)在涂料中的应用性能，包括其对常用树脂的溶解性能、挥发速率、安全性能等各方面性能进行了讨论，论证了DMC可以替代或部分替代传统有机溶剂应用于涂料中，对研制绿色环境友好的溶剂型涂料具有重要意义。%The application performances of dimethyl carbonate (DMC) in coatings, including dissolving properties of common resins, volatilization rates, security property and various aspects of performances were discussed. It demonstrates that DMC may replace or partly replace traditional organic solvents used in coatings. This is of great signiifcance for the development of environmental solvent-based coatings.
  • 摘要：对金塘大桥钢箱梁外表面涂层腐蚀情况进行了调查、评估，并根据调查结果，针对钢箱梁的上表面、下表面和连接部位制定了行之有效的维修涂料配套方案。经实际应用，钢箱梁整体的外观和防护都得到了改善。%Corrosion surface coats on the steel box girder of Jintang Bridge is investigated and evaluated. Based on ifndings, an effective corresponding program of maintenance coatings is formulated for top surface, undersurface and connections of the steel box girder. It has been proved in practical application that overall appearance and protection of the steel box girder are improved.
  • 摘要：To prepare an acrylic ester emulsion with outstanding seal performance, the acetate A is chosen as a crosslinking monomer of the emulsion to research the inlfuence of acetate A’s dosage and emulsion pH on sealing performance and heat storage stability of seal primer after ifve special metal salts are compared, and then its seal effect is tested on the basis of several substrates and compared with seal emulsions available in the market. The result shows:good seal performance of the primer can be obtained when the acetate A is used as the crosslinking monomer. As the crosslinking monomer dosage increases, the emulsion seal capacity rises but the heat storage stability decreases. As the emulsion pH increases, its heat storage stability rises up but the emulsion seal capacity decreases. When the crosslinking monomer dosage is 2% and emulsion pH is about 8.5~9, the sealing primer has good seal capacity and stability. The acrylic ester emulsions formulated in the experiment have good seal effects on several substrates and their seal capacity is superior to most products available in the market. The metallic self-crosslinking acrylic ester emulsion formulated in the experiment can effectively solve bleeding problem in painting of waterborne wood coatings.%为制备封闭性能优异的丙烯酸酯乳液，通过比较5种特殊金属盐后，选择醋酸盐A作为乳液的交联单体，研究了醋酸盐A的用量和乳液pH值对封闭底漆封闭性能和热贮存稳定性的影响，并在多种基材上测试其封闭效果及与市售封闭乳液作了比较。结果表明：采用醋酸盐A作交联单体，底漆封闭性能较好，随着交联单体用量增加，乳液封闭性能增强，热贮存稳定性降低，随着乳液pH值的提高，热贮存稳定性提高，乳液封闭性能降低，当交联单体用量为2%，乳液p H值在8.5～9时，制备的封闭底漆兼具良好的封闭性及稳定性，实验制备的丙烯酸酯乳液在多种基材上均具有较好的封闭效果，其封闭性能优于市面上的大多数产品。实验制备的金属自交联丙烯酸酯乳液有效解决水性木器涂料涂装中的渗色问题。
  • 摘要：A new acrylic modiifed alkyd resin was studied and prepared. The formula design and application from the aspects of production, application and iflm performances were researched. The mixed ratio of siritch and soybean oil at 8∶2 (mass ratio), xylene and 200# solvent oil at 7∶3 (mass ratio) were adopted. The prepared acrylic modiifed alkyd resin had good workability, mechanical properties and resistance. It was suitable for the application of construction machinery and the engineering facilities.%介绍一种新型丙烯酸改性醇酸树脂的研制过程，从生产工艺、施工应用、涂膜性能的角度探讨配方设计思路及工艺实现的方法。用8∶2(质量比)的胡麻油与豆油、7∶3(质量比)的二甲苯与200#工业用溶剂油为混合溶剂，制备的新型丙烯酸改性醇酸树脂，用其制得的白色涂料具有良好的施工性能和综合机械性能，能耐常见的介质，适用于工程机械、工程设施防护及装饰方面。
  • 摘要：In order to reduce the low surface energy of functional coatings, three acryloyl oxygen radicals isopropyl silane monomer, polyethylene glycol single methyl ether, butyl acrylate, ethyl methacrylate andγ-methyl acryloxy trimethyl silane are selected as monomers to prepare copolymer with low surface energy and organic silicon function. The appropriate monomer ratio, molecular weight and glass transition temperature are obtained through the properties characterization of the polymers. The optimal formula was obtained through the evaluation on the contact angle, adhesion strength, water resistance and antifouling property of coatings.%为了降低功能涂层的低表面能，选择丙烯酰氧基三异丙基硅烷单体与聚乙二醇单甲醚、丙烯酸丁酯、甲基丙烯酸乙酯、γ-甲基丙烯酰氧基三甲基硅烷作为共聚单体，制备低表面能有机硅功能共聚物。通过聚合物性能表征，得到适宜的单体配比、分子量和玻璃化温度。通过对涂层接触角、附着强度、耐水性、防污性评价，得出涂层最佳配方。
  • 摘要：十年之前的2006年，美丽的海滨城市青岛，在行业同仁的见证下，《中国涂料》杂志走过了她20岁的青春岁月；十年之后的2016年，新朋旧友再次共聚岛城，共同庆祝《中国涂料》三十而立。 30年，在历史的长河里，只是短短一瞬，但在《中国涂料》的创刊史上，却是令人回味悠长的漫长时光。有鉴于此，中国涂料工业协会《、中国涂料》杂志社有限公司在召开2016年中国涂料工业信息年会的同时，举办了《中国涂料》杂志创刊30周年的大型纪念活动。
  • 摘要：2016年迎来了《中国涂料》创办30周年华诞。在祝贺《中国涂料》发展的同时，自然会回忆它的发展史，和期待它的未来。 回忆记得《中国涂料》创办时，涂料行业还有《涂料工业》《涂料技术》《涂料文摘》等期刊，都创办得时间早，专业人员多，经验丰富，是我们学习的老大哥。为了提高我们的办刊水平，学习他们的经验，不断提高自己的办刊水平。

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