We propose a constructive algorithm that decomposes an arbitrary real tensor into a finite sum of orthonormal rank-1 outer products. The algorithm, called TTr1SVD, works by converting the tensor into a tensor-train rank-1 (TTr1) series via the singular value decomposition (SVD). TTr1SVD naturally generalizes the SVD to the tensor regime with properties such as uniqueness for a fixed order of indices, orthogonal rank-1 outer product terms, and easy truncation error quantification. Using an outer product column table it also allows, for the first time, a complete characterization of all tensors orthogonal with the original tensor. Incidentally, this leads to a strikingly simple constructive proof showing that the maximum rank of a real $2 imes 2 imes 2$ tensor over the real field is 3. We also derive a conversion of the TTr1 decomposition into a Tucker decomposition with a sparse core tensor. Numerical examples illustrate each of the favorable properties of the TTr1 decomposition.
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