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Modeling of One-Dimensional Smoldering of Polyurethane in Microgravity Conditions

机译:微重力条件下聚氨酯的一维闷烧建模

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摘要

Results are presented from a model of forward smoldering combustion of polyurethane foam in microgravity. The transient one-dimensional numerical-model is based on that developed at the University of Texas at Austin. The conservation equations of energy, species and mass in the porous solid and in the gas phases are numerically solved. The solid and the gas phase are not assumed to be in thermal or in chemical equilibrium. The chemical reactions modeled consist of foam oxidation and pyrolysis reactions, as well as char oxidation. The model has been modified to account for new polyurethane kinetics parameters and radial heat losses to the surrounding environment. The kinetics parameters are extracted from thermogravimetric analyses published in the literature and using Genetic Algorithms as the optimization technique. The model results are compared with previous tests of forward smoldering combustion in microgravity conducted aboard the NASA Space Shuttle. The model calculates well the propagation velocities and the overall smoldering characteristics. Direct comparison of the solution with the experimental temperature profiles shows that the model predicts well these profiles at high temperature, but not as well at lower temperatures. The effect of inlet gas velocity is examined and the minimum airflow for ignition identified. It is remarkable that this one-dimensional model with simplified kinetics is capable of predicting cases of smolder ignition but with no self-propagation away from the igniter region. The model is used for better understanding of the controlling mechanisms of smolder combustion for the purpose of fire safety, both in microgravity and normal gravity, and to extend the unique microgravity data to wider conditions avoiding the high cost of space-based experiments.
机译:结果从微重力下的聚氨酯泡沫正向阴燃燃烧模型给出。瞬态一维数值模型基于德克萨斯大学奥斯汀分校开发的模型。数值求解了多孔固体和气相中能量,种类和质量的守恒方程。不假定固相和气相处于热平衡或化学平衡。建模的化学反应包括泡沫氧化和热解反应以及炭氧化。该模型已经过修改,以考虑到新的聚氨酯动力学参数和向周围环境的径向热损失。动力学参数是从文献中发表的热重分析中提取的,并使用遗传算法作为优化技术。将模型结果与先前在NASA航天飞机上进行的微重力正向阴燃燃烧测试进行了比较。该模型可以很好地计算出传播速度和整体阴燃特性。将溶液与实验温度曲线进行直接比较表明,该模型在高温下可以很好地预测这些曲线,而在较低温度下则不能很好地预测。检查进气速度的影响,并确定点火的最小气流。值得注意的是,这种具有简化动力学的一维模型能够预测闷燃的情况,但不会在点火器区域之外进行自蔓延。该模型用于更好地了解在微重力和法向重力下闷烧燃烧的控制机制,以达到防火安全的目的,并将独特的微重力数据扩展到更宽的条件,从而避免了空基实验的高昂成本。

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