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Liquid-liquid extraction in an oscillating baffle column.

机译:在振荡挡板塔中进行液-液萃取。

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摘要

The oscillating baffle column presently described was invented by Dr.W.J.Thomas. It is a differentially operating continuous counter-current extractor. The experimental work is concerned with establishing the efficiency of the extractor under different conditions of operation up to the flooding point. Oscillating speeds and liquid flow rates were varied while other parameters were maintained constant. A direct comparison with the efficiency of operation of a Rotating Disc Contactor was made by carrying out the identical experiments in each case. The general differential equations for the extract and raf-finate phases in a differential contactor model have been derived by several methods. The relationship between the sign of each term in the differential equation and the direction of phase flow has been considered. The overall mass transfer coefficient in the extract phase, ka, has been measured along the column. It was found that a reversal in the trend in ka occurs depending on the speed of oscillation. At low oscillating speed ka is larger at the bottom of the column than the top and at high oscillating speeds the reverse is true. Three methods of calculating the longitudinal mixing coefficient from experimental data have been employed. The method using integration by parts is considered to be the most accurate and reliable. A dye injection technique was used to experimentally determine the C curve for different operating conditions for the Oscillating Baffle and the Rotating Disc Columns. A gamma function was used to relate the C curve to the variance and the longitudinal dispersion coefficient.
机译:目前描述的摆动挡板柱是由Dr.W.J.Thomas发明的。它是差动操作的连续逆流提取器。实验工作涉及在不同的操作条件下直至浸水点确定萃取器的效率。改变振荡速度和液体流速,同时保持其他参数不变。通过在每种情况下进行相同的实验,可以直接与转盘接触器的工作效率进行比较。差分接触器模型中萃取相和萃余相的一般微分方程已经通过几种方法导出。已经考虑了微分方程中每个项的符号与相流方向之间的关系。沿色谱柱测量了萃取相中的总传质系数ka。已经发现,ka趋势的逆转取决于振荡速度。在低振荡速度下,色谱柱底部的ka大于顶部,而在高振荡速度下,相反的情况成立。已经采用了三种根据实验数据计算纵向混合系数的方法。使用零件集成的方法被认为是最准确和可靠的。染料注入技术用于实验确定摆动挡板和转盘色谱柱在不同操作条件下的C曲线。使用伽马函数将C曲线与方差和纵向色散系数相关联。

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  • 作者

    Chiu Yao-Tyng.;

  • 作者单位
  • 年度 1967
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  • 原文格式 PDF
  • 正文语种 en
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