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Performance of pre-primed and finish coated galvannealed steel sheets for automotive bodies

机译:汽车车身用预涂底漆的涂层镀锌钢板的性能

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摘要

Coatings are used to enhance appearance and assure functional requirements. High performance and cost reduction during vehicle manufacturing are the main requirements, leading to increased use of pre-primed automotive sheet in recent years. Costs may be significantly reduced if the conventional electrophoretic primer is eliminated or its usage reduced. Conductive primers also offer the advantage of welding facility. The behaviour of two conductive pre-primers applied on galvannealed steel was studied and compared with that of a conventional electrophoretic primer. Before pre-priming a nonchrome pre-treatment was applied. Pre-primer 1 is an organic zinc rich silicate with a low thickness and pre-primer 2 is a very thin water based primer filled with graphite. The behaviour of two finish coat systems was also studied. These finish coats were applied on not primed and pre-primed galvannealed steel sheets. Two activation treatments were used, a conventional zinc phosphate and an experimental one. Finish coat system 1 included a powder intercoat, a waterborne base coat and a clear coat, and finish coat system 2 included the same powder intercoat, a solvent based base coat and a clear coat. Formability capabilities of pre-primers were evaluated through cupping and stone chipping tests. To evaluate corrosion protection, these samples were submitted to a cyclic corrosion test (CCT). Corrosion mechanisms were studied by scanning electron microscopy (SEM) with associated X-ray microanalysis by dispersive energy spectrometry (EDS) and by electrochemical impedance spectroscopy (EIS). To evaluate the performance of finish coats, the samples were also submitted to the same cyclic corrosion test, and the paint coating adhesion was evaluated, before and after exposure, by cross-cut test method. Both pre-primers applied with a low thickness seem to be good alternatives to the conventional electrophoretic primers. In agreement with results previously obtained for preprimed electrogalvanized steel substrate, submitted to CCT, electrochemical studies showed that less protection was achieved by primer 2. Regarding finish coats better adhesion was verified for the one with waterborne base coat, a more environmentally convenient system. Both finish coats presented good anticorrosive behaviour, without significant defects on undamaged areas.
机译:涂层用于增强外观并确保功能要求。主要要求是在汽车制造过程中实现高性能和降低成本,这导致近年来预涂底漆的汽车板的使用增加。如果取消传统的电泳底漆或减少其使用量,则可以显着降低成本。导电底漆还具有焊接设备的优势。研究了镀锌钢上两种导电底漆的行为,并将其与常规电泳底漆进行了比较。在预涂底漆之前,先进行无铬预处理。预底漆1是厚度薄的富含有机锌的硅酸盐,而预底漆2是填充石墨的非常薄的水基底漆。还研究了两种面漆体系的性能。将这些面漆涂在未上底漆和预底漆的热镀锌钢板上。使用了两种活化处理,一种是常规的磷酸锌,另一种是实验性的。面漆体系1包括粉末中间漆,水性底漆和清漆,而面漆体系2包括相同的粉末中间漆,溶剂基底漆和清漆。通过拔罐和碎石测试评估了底漆的可成型性。为了评估腐蚀防护性能,将这些样品进行了循环腐蚀测试(CCT)。通过扫描电子显微镜(SEM)以及通过分散能谱(EDS)和电化学阻抗谱(EIS)进行的相关X射线显微分析,研究了腐蚀机理。为了评估面漆的性能,还对样品进行了相同的循环腐蚀测试,并通过划格法测试了暴露前后的漆膜附着力。两种低厚度的预底漆似乎都是常规电泳底漆的不错选择。与先前提交给CCT的预涂锌电镀钢基材的结果一致,电化学研究表明底漆2的保护作用更少。关于面漆,对于水性底漆(一种更环保的体系),其附着力得到了验证。两种面漆都具​​有良好的防腐性能,在未损坏的区域没有明显的缺陷。

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