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Electrospinning of Cellulose and Carbon Nanotube-Cellulose Fibers for Smart Applications

机译:纤维素和碳纳米管纤维素纤维的静电纺丝,用于智能应用

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摘要

Cellulose is one of the Earth?s most abundant natural polymers and is used as a raw material in various applications. Recently, cellulose based electro-active paper (EAPap) has been investigated for its potential as a smart material. The electrospinning method of fiber production is not a new way of fabrication; however, it has attracted a great deal of attention as a means of producing non-woven membranes of nanofibers due to its simple methodology and the advent of nano applications. Electrospinning occurs when the electrical force on a polymer droplet overcomes its surface tension, and a charged jet is ejected. As the liquid jet is continuously elongated and the solvent is evaporated, the fibers of sub-micron size or nano size are formed, depending on the conditions. In a previous study, a cellulose mat was electro-spun and tested for piezoelectric characteristics. This aligned, electrospun cellulose mat showed a possibility as a promising smart material. Additionally, carbon nanotubes have been considered for the versatile nano-applications due to their superior material properties such as low density and high aspect ratio. Parametric studies were conducted to find optimum conditions for electrospinning. Various ways of reducing surface tension of solutions were investigated including radiative and convective heating of the solution. Pre-examination of solution is very important in consistent, uniform fiber formation. In this study, cellulose and CNT-cellulose composite fibers were prepared via electrospinning. The optimal experimental conditions for fiber generation were found so that the mechanical strength of both the composite and the pure cellulose fibers could be compared in future tests. Eventually, this fiber will be interwoven into the CNT-cellulose mat and be used as an electro-active paper sensor and actuator. The CNT-cellulose electrospun mat will be widely applicable to the fields of sensors, filters and reinforcements in composites because of its intrinsic properties of porosity, light weight, flexibility, and large surface area. To be used in the aforementioned applications, piezoelectric properties of this composite will also be tested in the next step.
机译:纤维素是地球上最丰富的天然聚合物之一,在各种应用中被用作原材料。最近,人们已经研究了纤维素基电活性纸(EAPap)作为智能材料的潜力。纤维生产的静电纺丝方法并不是一种新的制造方法;然而,由于其简单的方法和纳米应用的出现,它作为生产纳米纤维非织造膜的一种方法引起了广泛的关注。当聚合物小滴上的电场力克服其表面张力,并喷射出带电射流时,就会发生静电纺丝。随着液体射流的连续伸长和溶剂的蒸发,取决于条件,形成了亚微米尺寸或纳米尺寸的纤维。在先前的研究中,对纤维素毡进行了电纺并测试了压电特性。这种对齐的静电纺纤维素垫显示出作为有前途的智能材料的可能性。另外,由于碳纳米管具有优异的材料特性,例如低密度和高长宽比,它们已被考虑用于多功能纳米应用。进行了参数研究,以找到静电纺丝的最佳条件。研究了降低溶液表面张力的各种方法,包括溶液的辐射加热和对流加热。溶液的预检查对于一致,均匀的纤维形成非常重要。在这项研究中,纤维素和CNT-纤维素复合纤维是通过静电纺丝制备的。找到了纤维生成的最佳实验条件,以便可以在将来的测试中比较复合材料和纯纤维素纤维的机械强度。最终,该纤维将交织到CNT纤维素毡中,并用作电活性纸传感器和致动器。 CNT纤维素电纺垫由于其固有的孔隙率,重量轻,柔韧性和大表面积特性,将广泛应用于复合材料中的传感器,过滤器和增强材料领域。为了在上述应用中使用,该复合材料的压电性能还将在下一步中进行测试。

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    Pankonien Alexander;

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  • 年度 2008
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