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Determination of the solidus and liquidus temperatures of the real-steel grades with dynamic thermal-analysis methods

机译:用动态热分析方法测定真实钢种的固相线和液相线温度

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摘要

The knowledge of the solidus and liquidus temperatures of the real-steel grades is one of the most important technologicalfactors – especially when dealing with the processes of casting and solidification. These temperatures are critical parameters forproper settings of the models (physical or numerical) or in the final stage of an applied research of a real process. A correctsetting of a production technology is significantly affecting the final quality of the as-cast steel (billets or ingots). Therefore, thispaper is devoted to discussing the findings obtained during a utilization of dynamic thermal-analysis methods to identify thesolidus and liquidus temperatures applicable to commercially produced steels. The results obtained with a differential thermalanalysis (DTA) for three steel grades and with 3D differential scanning calorimetry (3D DSC) for two steel grades are comparedwith the results of the selected equations commonly used for liquidus and/or solidus temperature calculations. The calculationsobtained with the Computherm SW for the discussed steels were also realized.It can be stated that the equilibrium liquidus and solidus temperatures obtained with the above-mentioned methods for each steelgrade differ. The differences between the calculated results, the thermodynamic calculations and thermal-analysis results arevery unpredictable and vary individually for different steels. These differences are not marginal (tens of Celsius degrees). So, itis sometimes suitable to combine several methods for a proper determination of the liquidus and solidus temperatures for acorrect setting of a steel-making process or its modelling. The best solution for a technological process is to obtain the liquidusand solidus temperatures for a concrete-steel grade from a given steelmaking practice – a thermal analysis of a concrete-steelgrade is a possible way.
机译:真正钢种的固相线和液相线温度的知识是最重要的技术因素之一,尤其是在处理铸造和凝固过程时。这些温度是正确设置模型(物理或数值)或在实际过程的应用研究的最后阶段的关键参数。生产技术的正确设置会严重影响铸态钢(方坯或铸锭)的最终质量。因此,本文致力于讨论在利用动态热分析方法确定适用于商业生产钢的固相线和液相线温度期间获得的发现。将使用三种钢的差热分析(​​DTA)和使用两种钢的3D差示扫描量热法(3D DSC)获得的结果与通常用于液相线和/或固相线温度计算的所选方程式的结果进行比较。还可以使用Computherm SW对所讨论的钢进行计算。可以说,用上述方法获得的每种钢种的平衡液相线和固相线温度是不同的。计算结果,热力学计算结果和热分析结果之间的差异非常难以预测,并且对于不同的钢会有所不同。这些差异不是很小的(数十摄氏度)。因此,有时适合将几种方法结合起来,以正确确定液相线和固相线温度,从而正确设定炼钢工艺或其模型。工艺过程的最佳解决方案是从给定的炼钢实践中获得混凝土-钢种的液相线和固相线温度–一种可行的方法是对混凝土-钢种进行热分析。

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