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A Comparative Study on the Carbon Products from Hydrothermal Carbonization and Torrefaction Process Using Wood Fiber Waste

机译:木纤维废料水热碳化和干馏过程中碳产物的比较研究

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摘要

Wood fiber waste is the one important biomass energy source to convert to value added product which is carbon particles. Hydrothermal carbonization (HTC) is the effective method to convert this biomass into carbon particles. The undesirable properties of biomass such as high moisture content and its heterogeneous nature pose a barrier to its competitiveness in the energy generation market. A best option to overcome the issues face with biomass is to carry out a pretreatment process called torrefaction. The physical characteristic of the carbon particles was determined by using FTIR, BET and FESEM. The main objectives of this study are to prepare carbon particles from hydrothermal carbonization and Torrefaction process using wood fiber waste and to identify physical characterization of carbon particle from the both processes. Proximate analysis has been done to identify the changes in chemical composition of the product. Based on the analysed, the product with higher energy density, low moisture content was produced from Torrefaction process. Torrefaction process produced lowest moisture content product which is about 3.99% to 4.47%. Ash content also shows that torrefaction process produced product with lowest percentage ash content compared to HTC and raw of wood fiber waste. The volatile matter left is from 53% to 91% for all the samples. Torrefaction also produce highest calorific value (24.894MJ/kg). FTIR analysis showed the hydroxyl, carbonyl, aliphatic, ethers, alcohol, phenol and carboxylic groups are present on the surface of the sample. Finally, it can be concluded that both processes is practicable method to convert biomass into value added product.
机译:木纤维废物是一种重要的生物质能源,可转化为碳颗粒等增值产品。水热碳化(HTC)是将这种生物质转化为碳颗粒的有效方法。生物质的不良特性(例如高水分含量及其异质性)构成了其在能源发电市场中竞争力的障碍。克服生物质面临的问题的最佳选择是进行称为烘焙的预处理过程。碳颗粒的物理特性是通过FTIR,BET和FESEM确定的。这项研究的主要目的是使用木纤维废料通过水热碳化和烘焙过程制备碳颗粒,并从这两种过程中鉴定碳颗粒的物理特征。已进行了近距离分析以识别产品化学成分的变化。在分析的基础上,通过焙烧法生产了能量密度高,水分含量低的产品。焙干过程产生的最低水分含量产品约为3.99%至4.47%。灰分含量还表明,与HTC和木纤维废料相比,焙干工艺生产的产品具有最低的灰分百分比。所有样品的残留挥发物含量从53%到91%。烘焙也产生最高的发热量(24.894MJ / kg)。 FTIR分析表明,样品表面上存在羟基,羰基,脂肪族,醚,醇,酚和羧基。最后,可以得出结论,这两个过程都是将生物质转化为增值产品的可行方法。

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    Noor Azlinna Abu Bakar;

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  • 年度 2013
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