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Why Is There an “Inert” Metal Center in the Active Site of Nitrile Hydratase? Reactivity and Ligand Dissociation from a Five-Coordinate Co(III) Nitrile Hydratase Model

机译：为什么丁腈酶的活性位点有“惰性”金属中心？五坐标CO（III）腈水合酶模型的反应性和配体离解

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Jason Shearer; Irene Y. Kung; Scott Lovell; Werner Kaminsky; Julie A. Kovacs;
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1. Oxidation of metal-bound thiolato sulfur centers in Fe(III) and Co(III) complexes with carboxamido nitrogens and thiolato sulfurs as donors: Relevance to the active sites of nitrile hydratases [J] . Tyler LA., Olmstead MM., Mascharak PK., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1999,第4期

机译：Fe（III）和Co（III）配合物中金属结合的硫醇基硫中心的氧化，以羧酰胺氮和硫醇基硫为供体：与腈水合酶活性位点的相关性
2. Modeling the Active Site of Nitrile Hydratase:Synthetic Strategies to Ensure Simultaneous Coordination of Carboxamido-N and Thiolato-S to Fe(III)Centers [J] . Todd C.Harrop, Marilyn M.Olmstead, Pradip K.Mascharak Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第25期

机译：建模腈水合酶的活性位点：合成策略，以确保Carboxamido-N和Thiolato-S与Fe（III）中心同时协调
3. Co-III complexes with square-planar N2S2- and N-2(SO2)(2)-type ligands as an active site structural model for nitrile hydratase - Biological implications of an amidate coordination [J] . Yano T, Arii H, Yamaguchi S, European journal of inorganic chemistry . 2006,第18期

机译：Co-III配合物与方形平面N2S2-和N-2（SO2）（2）型配体作为腈水合酶的活性位点结构模型-酰胺化物配位的生物学意义
4. N_2S_3X-Fe Models of Nitrile Hydratase [C] . Annual meeting of the ACS Central Region . 2009

机译：N_2S_3X-FE模型的丁腈酶
5. Biomimetic models of the active site of the metalloenzyme nitrile hydratase. [D] . Schweitzer, Dirk. 2001

机译：金属酶腈水合酶活性位点的仿生模型。
6. Why Is There an Inert Metal Center in the Active Site of Nitrile Hydratase? Reactivity and Ligand Dissociation from a Five-Coordinate Co(III) Nitrile Hydratase Model [O] . Jason Shearer, Irene Y. Kung, Scott Lovell, -1

机译：为什么在腈水合酶的活性部位存在惰性金属中心？五坐标的Co（III）腈水合酶模型的反应性和配体解离
7. Modeling the Active Site of Nitrile Hydratase: Synthetic Strategies to Ensure Simultaneous Coordination of Carboxamido-N and Thiolato-S to Fe(III) Centers [O] . -1

机译：建模丁腈水溶胶酶的活性位点：合成策略，以确保羧酰胺-N和硫醇盐〜Fe（III）中心的同时协调

Why Is There an “Inert” Metal Center in the Active Site of Nitrile Hydratase? Reactivity and Ligand Dissociation from a Five-Coordinate Co(III) Nitrile Hydratase Model

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