BENZOTRIFLUORIDE: CHEMICAL THERMODYNAMIC PROPERTIES AND INTERNAL ROTATION

摘要

The chemical thermodynamic properties in the vapor state (0 to 1500°K.) were calculated by methods of statistical mechanics. Experimental studies provided the following information: Values of heat capacity for the solid (12°K. to the triple point), the liquid (triple point to 370°K.) and the vapor (363 to 500°K.); the triple point temperature; the heat of fusion; thermodynamic functions for the solid and liquid (0 to 370°K.); heat of vaporization (334 to 375°K.)second virial coefficient (334 to 500°K.); and vapor pressure (328 to 412°K.).