Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998-2002 Tropical Ozone Climatology, 3

摘要

Abstract: Since 1998 the Southern Hemisphere ADditional OZonesondes (SHADOZ) project has collected more than 2000 ozone profiles from a dozen tropical and subtropical sites using balloon-borne electrochemical concentration cell (ECC) ozonesondes. The data (with accompanying pressure-temperature-humidity soundings) are archived. Analysis of ozonesonde imprecision within the SHADOZ dataset revealed that variations in ozonesonde technique could lead to station-to-station biases in the measurements. In this paper imprecisions and accuracy in the SHADOZ dataset are examined in light of new data. When SHADOZ total ozone column amounts are compared to version 8 TOMS (2004 release), discrepancies between sonde and satellite datasets decline 1-2 percentage points on average, compared to version 7 TOMS. Variability among stations is evaluated using total ozone normalized to TOMS and results of laboratory tests on ozonesondes (JOSE-2O00, Julich Ozonesonde Intercomparison Experiment). Ozone deviations from a standard instrument in the JOSE flight simulation chamber resemble those of SHADOZ station data relative to a SHADOZ-defined climatological reference. Certain systematic variations in SHADOZ ozone profiles are accounted for by differences in solution composition, data processing and instrument (manufacturer). Instrument bias leads to a greater ozone measurement above 25 km over Nairobi and to lower total column ozone at three Pacific sites compared to other SHADOZ stations at 0-20 deg.S.