THE REACTION BETWEEN OXYGEN DIFLUORIDE AND DIBORANE : Ⅱ.THE KINETICS AND A PROPOSED MECHANISM

摘要

For the reaction between OF2 and B2H6, the initial rates of consumption of OF2 and B2H6 and the initial rate of formation of BF3 (a reaction product) were experimentally determined over a range of initial partial pressures of 1-30 torr for B2H6 and 5-40 torr for OF2, at 300°K. In addition, the initial consumption rates of OF2 and of B2H6 were determined at temperatures ranging from 300-330°K.