Reactions of Hexafluoroacetone, Hexafluoropropene, and Tetrafluoroethylene with Bis(cyclo-octa-1,5-diene)platinum; Molecular Structure of (Pt2((CF3)sub 2CO)(1,5-C8H12)sub 2).

摘要

Treatment of (Pt(COD)2) (COD = cyclo-octa-1,5-diene) with hexafluoroacetone affords dinuclear or mononuclear platinum complexes, whereas tetrafluoroethylene gives a steroeochemically non-rigid octafluoro-1,4-diplatinacyclohexane, and hexafluoropropene yields a dinuclear carbene-bridged complex. (Author)