Synthesis of Open-Chain Poly(Difluorophosphazene) and Its Reactions with Alkoxides, Aryloxides, and Amines.

摘要

The first preparation of soluble poly(difluorophosphazene) is described, together with its reactions with alkoxides, aryloxide, and amines. Amines replace only one fluorine per phosphorus. Mechanistic explanations are suggested on the basis of model compound reactions with cyclic phosphazenes. (Author)