Rational Synthesis of Unidimensional Mixed Valence Solids. Structural, Spectral, and Electrical Studies of Charge Distribution and Transport in Partially Oxidized Nickel and Palladium Bisdiphenylglyoximates.

摘要

This paper presents a detailed study of solid state structure, oxidation state, and electron transport in Ni(dpg)2I and Pd(dpg)2I, dpg = diphenylglyoximato. The crystal structure of Ni(dpg)2I has been studied by x-ray diffraction at 23 and -160 C.