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Useful Zinc Reagent for the Preparation of 2-Oxo-1,1-Difluoroalkylphosphonates

机译：用于制备2-氧代-1,1-二氟烷基膦酸酯的有用锌试剂

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The treatment of dialkyl bromodifluoromethylphosphonates with activated zinc dust in various solvents gave dialkoxyphosphinyldifluoromethylzinc compounds 2, which were acylated with acid halides or fluorinated acid anhydride to afford dialkyl 2-oxe-1, 1-difluoroalkylphosphonates in good yields.

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作者
Burton, D. J.; Ishihara, T.; Maruta, M.;
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年度 1982
页码 p.1-6
总页数 6
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Organometallic compounds; Phosphonates; Synthesis(Chemistry); Acids; Activation; Acylation; Anhydrides; Chemical agents; Dust; Fluorination; Fluorine compounds; Halides; Solvents; Alkyl radicals; Reprints;

机译：有机金属化合物;膦酸盐;合成（化学）;酸;活化;酰化;酸酐;化学试剂;粉尘;氟化;氟化合物;卤化物;溶剂;烷基;重印;

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1. Highly regioselective addition of organozinc reagents to 2-Oxo-1,2-dihydropyrimidine-5-carboxylates activated by BF_3· OEt_2: Synthesis of 2-Oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylates [J] . Singh K., Chopra R. European journal of organic chemistry . 2013,第27期

机译：在BF_3·OEt_2活化的2-Oxo-1,2-二氢嘧啶-5-羧酸酯中高度区域选择性地添加有机锌试剂：2-Oxo-1,2,3,4-四氢嘧啶-5-羧酸酯的合成
2. GENERAL METHOD FOR PREPARATION OF ALLENIC ZINC REAGENTS BY THREE-CARBON HOMOLOGATION OF TRIORGANOZINCATES - CONVERGENT THREE-COMPONENT COUPLING OF PROPARGYLIC SUBSTRATES, TRIORGANOZINCATES, AND ELECTROPHILIC REAGENTS [J] . Harada T, Katsuhira T, Osada A, Journal of the American Chemical Society . 1996,第46期

机译：三碳素三碳同系物制备过敏性锌试剂的一般方法-聚合基质，三有机锌和亲电试剂的聚合三成分偶联
3. Synthesis and crystal structures of bis(tetraethylammonium)-(2-oxo-1,3-dithiole-4,5-dithiolato)zincate(II) and bis(tetra-n-butylammonium)(2-oxo-1,3-dithiole-4,5-dithiolato)zincate(II) [J] . Muller H., Narymbetov BZ., Zorina LV., Zeitschrift fur Anorganische und Allgemeine Chemie . 1998,第9期

机译：双（四乙基铵）-（2-氧代-1,3-二硫代-4,5-二硫代戊基）锌酸酯（II）和双（四正丁基铵）（2-氧代-1,3-二硫代）的合成和晶体结构-4,5-二硫拉托）zincate（II）
4. Selection of organic acid leaching reagent for recovery of zinc and manganese from zinc-carbon and alkaline spent batteries [C] . Yuliusman, R A Amiliana, P T Wulandari International Conference on Advanced Materials for Better Future . 2018

机译：从锌 - 碳和碱金属电池中选择有机酸浸出试剂的锌和锰
5. I. Mechanistic studies of a copper-catalyzed electrophilic amination of diorganozinc reagents by O-benzoyl N,N-dialkylhydroxylamines II. Development of a 3-exo-dig cyclization for the preparation of vinylidene cyclopropanes III. Total synthesis of (+)-polyanthellin A. [D] . Campbell, Matthew James. 2009

机译：I.O-苯甲酰基N，N-二烷基羟胺对铜催化的二有机锌试剂的亲电胺化的机理研究。 3-exo-dig环化反应用于制备亚乙烯基环丙烷III的开发。（+）-聚anthellin A的全合成。
6. Preparation and Purification of Zinc Sulphinate Reagents for Organic Synthesis [O] . Fionn O’Hara, Ryan D. Baxter, Alexander G. O’Brien, -1

机译：用于有机合成的亚硫酸锌试剂的制备和纯化
7. A USEFUL ZINC REAGENT FOR THE PREPARATION OF 2-OXO-1,1-DIFLUOROALKYLPHOSPHONATES [O] . Donald J. Burton, Takashi Ishihara, Masamichi Maruta 1982

机译：用于制备2-氧代-1,1-二氟烷基膦酸盐的有用锌试剂
8. Palladium Catalyzed Coupling of F-Vinyl Zinc Reagents with Aryl Iodides. An Improved Synthesis of Alpha, Beta, Beta-Trifluorostyrenes and the Stereospecific Preparation of 1-Phenyl-F-Propenes [R] . Heinze, P. L., Burton, D. J. 1986

机译：钯催化F-乙烯基锌试剂与芳基碘化物的偶联。 α，β，β-三氟苯乙烯的改进合成及1-苯基-F-丙烯的立体特异性制备

Useful Zinc Reagent for the Preparation of 2-Oxo-1,1-Difluoroalkylphosphonates

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