Study of Some Early Transition Metals in Oxidation State IV Using the Potassium Poly(pyrazolyl)borates as Ligands

摘要

The primary purpose of this investigation was to gain a better understanding of the fundamental chemistry of the early transition elements in their high oxidation states. The work involved the preparation and characterization of titanium, zirconium and hafnium poly(prazolyl) borate complexes with emphasis on the structure, mode of bonding and magnetic behavior of these complexes.