Structural Aspects of the Polyaniline Family of Electronic Polymers.(Reannouncement with New Availability Information)

摘要

Recent structural studies of the polyaniline family of electronic polymers in thebase and salt forms are reviewed. We describe the crystalline and amorphous structures of the two classes of emeraldine. The structural evolution with HCl doping and ring substitutions are also discussed in relationship with the electronic properties of these materials. Implications for charge transport phenomena are also considered....Polyaniline, Amorphous, Crystalline, Ring substitutions, Charge transport, 3-D Electronic Delocalization, Ring tilt angles, Interchain separations, Nucleate, Steric interactions, Flexible system.