Chemical and electrochemical parameters have been modified in the potentiostatic electropolymerization of polyfurane films doped with perchlorated anions (PFu/ClO4) in order to systematize the formation of this conducting polyaromatic compound in aprotic media. The study revealed a strong correlation between the electrochemical generation of black, adherent, ordered and conducting PFu/ClO4 films and the applied overpotential. Moreover, dopant concentration must be equal to or lower than monomer concentration due to the inhibition effect of the ClO4- anion. (C) 1998 Elsevier Science S.A. [References: 33]
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