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Production and Properties of Spin-Coated Cassava-Starch-GlyceroI-Beeswax Films

机译:旋涂木薯淀粉淀粉甘油糖蜡膜的制备及性能

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摘要

Cassava-starch based polymer films containing glycerol as a plasticizer (1.0-2.5-5.0%, w/w) and different lipids as additives (paraffin, stearyl alcohol, and beeswax- 0.25-0.5-1.0%, w/w) were produced. Control films were produced by heating a mixtureof glycerol, starch, and water, while treated films were produced by the addition of lipids/ ethanol solutions. The solutions were kept at around 70°C during amalgamation, and once congealed, were placed in a vacuum oven for 1 h at 90°C. The solutionswere then spun on 7-inch diameter non-stick disks, allowed to dry, and conditioned at 23°C and 50% RH before testing. Cassava starch-glycerol-beeswax films were successfully produced with a stable film structure at glycerol concentration equal or below5% (w/ w). Addition of glycerol and beeswax did not visually change the color of the films. Increasing glycerol content improved elongation while decreasing tensile strength. Increasing the glycerol concentration from 1.0 to 5.0% increased the water vapor permeability by 150% and addition of beeswax further increased these values by 250%.
机译:制作了基于木薯淀粉的聚合物膜,该膜含有甘油作为增塑剂(1.0-2.5-5.0%,w / w)和不同的脂质作为添加剂(石蜡,硬脂醇和蜂蜡-0.25-0.5-1.0%,w / w) 。通过加热甘油,淀粉和水的混合物来制备对照膜,而通过添加脂质/乙醇溶液来制备处理过的膜。溶液在合并过程中保持在70°C左右,一旦凝固,将其在90°C的真空烘箱中放置1小时。然后将溶液旋涂在直径为7英寸的不粘盘上,使其干燥,并在测试前在23°C和50%RH的条件下进行处理。成功生产了木薯淀粉-甘油-蜂蜡膜,其甘油浓度等于或低于5%(w / w)时具有稳定的膜结构。甘油和蜂蜡的添加在视觉上没有改变膜的颜色。甘油含量的增加改善了伸长率,同时降低了拉伸强度。将甘油浓度从1.0%增加到5.0%,可使水蒸气渗透率增加150%,而添加蜂蜡则将这些值进一步增加250%。

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