Radiative electronic energy transfer-time studies of naphthalene-biacetyl system by one and two-photon excitation, and optical antenna mechanism

摘要

In principle, the optical energy absorbed by a complex molecule raises that molecule to one of its excited states, and afterwards this excitation energy decays through the relaxation channels. Initially, electronically excited naphthalene emits photons and these emitted photons are absorbed by the acceptor molecule biacetyl, then excited biacetyl fluoresces. In this investigation radiative energy transfer-time is measured in cyclohexane by one and two-photon excitations. The UV-vis spectrum of biacetyl vapor at room temperature conditions was broad and structureless. (c) 2004 Elsevier B.V. All rights reserved.