Heteroligand lanthanide dialkyldithiocarbamate complexes with 1,10-phenanthroline:a new approacht o synthesis and application for the preparation of sulfides

摘要

A new simple method of synthesis of heteroligand complexes [Ln(Dalkdtc)_3Phen](Ln=Eu or Er;Dalkdtc is the dialkyldithiocarbamate ion,Phenis o-phenanthroline) in an aqueous solution isdescribed;the possibility of using the complexes as initial reagents for the synthesisof rare-earth sulfides is shown.