Preparation and characterization of lotus ceramics with different pore sizes and their implication for the generation of microbubbles for CO_2 sequestration applications

摘要

Four kinds of porous mullite ceramics, named lotus ceramics because of the similarity of their microstructure with lotus roots, were prepared by an extrusion method using rayon fibers of four different diameters (8.1, 9.6, 16.8 and 37.6 urn) as the pore formers. The physicochemical properties of these samples were characterized to test their applicability for the generation of microbubbles. The lotus ceramic samples contained pores of 9.4, 10, 15.6 and 30 urn size and porosities of 45-48%. SEM micrographs confirmed that the cylindrical pores were oriented unidirectionally along the extrusion direction and the degree of alignment was greater with larger fiber diameter. The permeability for gaseous CO_2 increased with increasing pore size from 3 x 10~(-13) to 8 x 10~~(-13) m~2. The four lotus ceramic samples, a commercial air stone (72 μm) and two simple tubes (1000 and 3500 um) were used to generate microbubbles in water under ambient conditions from a gas mixture of CO_2 and air. It was found that the bubble size could be decreased with bubblers of smaller pore size. In the bubble size measurements for pure CO_2 and air, the air bubbles were larger than the CO_2 bubbles due to partial dissolution of CO_2 into the water during bubbling. In order to generate smaller size bubbles using porous ceramic bubblers, the liquid must penetrate through the pores of the lotus ceramics before the gas is introduced into the system.