New Supported β-Amino Alcohols as Efficient Catalysts for the Enantioselective Addition of Diethylzinc to Benzaldehyde under Flow Conditions

M. Isabel Burguete; Eduardo Garcia-Verdugo; Maria J. Vicent; Santiago V. Luis; Helmut Pennemann; Nikolai Graf von Keyserling; Jurgen Martens

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New Supported β-Amino Alcohols as Efficient Catalysts for the Enantioselective Addition of Diethylzinc to Benzaldehyde under Flow Conditions

机译：新型负载型β-氨基醇作为流动条件下二乙基锌对苯甲醛对映选择性加成的高效催化剂

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Polymeric monoliths 10 containing an amino alcohol moiety derived from an industrial waste material represent one of the best ligands for the enantioselective catalytic addition of ZnEt_2 to benzaldehyde (99% ee), being recoverable and usable under flow conditions.

机译：含有衍生自工业废料的氨基醇部分的聚合物整料10是将ZnEt_2对映选择性催化加成至苯甲醛（99％ee）的最佳配体之一，可在流动条件下回收和使用。

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《Organic letters》 |2002年第22期|共4页
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M. Isabel Burguete; Eduardo Garcia-Verdugo; Maria J. Vicent; Santiago V. Luis; Helmut Pennemann; Nikolai Graf von Keyserling; Jurgen Martens;
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中图分类有机化学;
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1. New Supported β-Amino Alcohols as Efficient Catalysts for the Enantioselective Addition of Diethylzinc to Benzaldehyde under Flow Conditions [J] . M. Isabel Burguete, Eduardo Garcia-Verdugo, Maria J. Vicent, Organic letters . 2002,第22期

机译：新型负载型β-氨基醇作为流动条件下二乙基锌对苯甲醛对映选择性加成的高效催化剂
2. Development of small focused libraries of supported amino alcohols as an efficient strategy for the optimization of enantioselective heterogeneous catalysts for the ZnEt2 addition to benzaldehyde [J] . Burguete MI., Collado M., Garcia-Verdugo E., Tetrahedron . 2003,第10期

机译：开发小型的支持氨基醇的小型聚焦库，作为优化对苯甲醛中ZnEt2的对映选择性非均相催化剂的有效策略
3. Screening of amino sulfur ferrocenes as catalysts for the enantioselective addition of diethylzinc to benzaldehyde [J] . Grach G, Reboul V, Metzner P Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2008,第14期

机译：筛选氨基硫二茂铁作为对苯甲醛对映选择性加成二乙基锌的催化剂
4. Sugar Based g-Amino Alcohol Organocatalyst for Enantioselective Michael Addition of β-Keto Esters with Nitroolefins [C] . Divakar Ganesan, Chigusa Seki, Koji Uwai 日本化学会春季年会講演予稿集 . 2018

机译：糖基G-氨基酒精有机催化剂用于对映选择性的迈克尔加入亚硝烯烃的β-酮酯
5. The development of amino acid-derived catalysts for the enantioselective silylation of alcohols: An application to the total synthesis of sapinofuranone A [D] . Rodrigo, Jason M. 2010

机译：用于醇的对映选择性甲硅烷基化的氨基酸衍生催化剂的开发：在山茱ap呋喃酮A的全合成中的应用
6. Metal-mediated aminocatalysis provides mild conditions: Enantioselective Michael addition mediated by primary amino catalysts and alkali-metal ions [O] . Matthias Leven, Jörg M Neudörfl, Bernd Goldfuss 2013

机译：金属介导的氨基催化提供了温和的条件：伯氨基催化剂和碱金属离子介导的对映选择性迈克尔加成
7. Chiral Aryl Pyridyl Alcohols as Enantioselective Catalysts in the Addition of Diethylzinc to Substituted Benzaldehydes [O] . Tien-chu Chang, Chinpiao Chen 2015

机译：手性芳基吡啶醇作为对映选择性催化剂在二乙基锌加成取代苯甲醛中的应用
8. Chiral Oxazaborolidines as Catalysts for the Enantioselective Addition of Diethylzinc to Aldehydes [R] . Joshi, N. N., Srebnik, M., Brown, H. C. 1989

机译：手性恶唑硼烷作为二乙基锌对醛的不对称加成催化剂

New Supported β-Amino Alcohols as Efficient Catalysts for the Enantioselective Addition of Diethylzinc to Benzaldehyde under Flow Conditions

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