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Luminescence of Free and Self-Trapped Excitons in J-aggregates of Quino-2-Monomethine Cyanine

机译:奎诺2-单甲胺菁菁J聚集体中自由和自陷激子的发光

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摘要

Time-resolved luminescence spectra of J-aggregates of quino-2-monomethine cyanine containing real exciton traps are studied. It is found that free excitons are more efficiently quenched by the traps than the self-trapped ones. The structures of quino-2-monomethine cyanine J-aggregates in the dimethylformamide-water solution and Langmuir-Blodgett film are analyzed, and the applicability of the adiabatic theory of exciton self-trapping to the interpretation of experimental data are discussed.
机译:研究了含真实激子陷阱的喹-2-单甲亚菁花菁J聚集体的时间分辨发光光谱。发现自激陷阱比自陷陷阱更有效地淬灭了自由激子。分析了二甲基甲酰胺-水溶液和Langmuir-Blodgett膜中喹-2-单甲胺花青J-聚集体的结构,并讨论了激子自陷的绝热理论在实验数据解释中的适用性。

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