Suzuki-Miyaura Reaction in Water, Catalyzed by Palladium Nanoparticles Stabilized by Pluronic F68 Triblock Copolymer

A. N. Kashin; I. P. Beletskaya

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Suzuki-Miyaura Reaction in Water, Catalyzed by Palladium Nanoparticles Stabilized by Pluronic F68 Triblock Copolymer

机译：Pluronic F68三嵌段共聚物稳定的钯纳米颗粒催化的水中Suzuki-Miyaura反应

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摘要

Palladium nanoparticles stabilized by Pluronic F68 triblock copolymer effectively catalyzed Suzuki-Miyaura reaction in water. The reactions with water-soluble aryl iodides and aryl bromides containing electron-withdrawing or electron-donating substituent occurred at room temperature. The catalytic efficiency was found to depend on the size of palladium nanoparticles and their morphology.

机译：通过Pluronic F68三嵌段共聚物稳定的钯纳米粒子可有效催化水中的Suzuki-Miyaura反应。与含有吸电子或供电子取代基的水溶性芳基碘化物和芳基溴化物的反应在室温下发生。发现催化效率取决于钯纳米颗粒的尺寸及其形态。

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《Russian Journal of Organic Chemistry》 |2011年第4期|共5页
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A. N. Kashin; I. P. Beletskaya;
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正文语种 eng
中图分类有机化学;
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1. Suzuki-Miyaura Reaction in Water, Catalyzed by Palladium Nanoparticles Stabilized by Pluronic F68 Triblock Copolymer [J] . A. N. Kashin, I. P. Beletskaya Russian Journal of Organic Chemistry . 2011,第4期

机译：Pluronic F68三嵌段共聚物稳定的钯纳米颗粒催化的水中Suzuki-Miyaura反应
2. Antimicrobial effectiveness of silver nanoparticles co-stabilized by the bioactive copolymer pluronic F68 [J] . Carolina Alves dos Santos, Angela Faustino Jozala, Adalberto Pessoa Jr, Journal of Nanobiotechnology . 2012,第1期

机译：生物活性共聚物普朗尼克F68共同稳定的银纳米颗粒的抗菌效果
3. Water-soluble surface-anchored gold and palladium nanoparticles stabilized by exchange of low molecular weight ligands with biamphiphilic triblock copolymers [J] . Azzam T, Bronstein L, Eisenberg A Langmuir: The ACS Journal of Surfaces and Colloids . 2008,第13期

机译：通过将低分子量配体与双亲三嵌段共聚物交换而稳定的水溶性表面锚定金和钯纳米粒子
4. SOLID NANOPARTICLES TO STABILIZE WATER/-OIL EMULSIONS AND CATALYZE REACTIONS ATTHE LIQUID/LIQUID INTERFACE [C] . Steven Crossley, Jimmy Faria, Min Shen American Chemical Society National Meeting . 2010

机译：固体纳米颗粒以稳定水/ -OIL乳液和催化反应在液体/液体界面
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Antimicrobial effectiveness of silver nanoparticles co-stabilized by the bioactive copolymer pluronic F68 [O] . Carolina Alves dos Santos, Angela Faustino Jozala, Adalberto Pessoa Jr, 2012

机译：生物活性共聚物普朗尼克F68共同稳定的银纳米颗粒的抗菌效果
7. Antimicrobial effectiveness of silver nanoparticles co-stabilized by the bioactive copolymer pluronic F68 [O] . dos Santos, Carolina A, Jozala, Angela F, Pessoa Jr, Adalberto, 2015

机译：生物活性共聚物普朗尼克F68共同稳定的银纳米颗粒的抗菌效果

Suzuki-Miyaura Reaction in Water, Catalyzed by Palladium Nanoparticles Stabilized by Pluronic F68 Triblock Copolymer

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