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首页> 外文期刊>Russian Journal of General Chemistry >On the Composition of Copper(II), Cobalt(II), and Nickel(II) Complexes with Some 3,6-Disubstituted 1,2,4,5-Tetrazines
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On the Composition of Copper(II), Cobalt(II), and Nickel(II) Complexes with Some 3,6-Disubstituted 1,2,4,5-Tetrazines

机译:关于含3,6-二取代的1,2,4,5-四嗪的铜(II),钴(II)和镍(II)配合物的组成

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摘要

Complex formation in the systems containing copper(II), cobalt(II) and nickel(II) ions (M) and 3-(3,5-dimethylpyrazol-1-yl)-6-R-1,2,4,5-tetrazines (R = 2-hydroxyethylamino, piperidino) (L) was studied by voltammetry and spectrophotometry. Cu(II), Co(II) and Ni(II) were found to form complex compounds with derivatives of 1,2,4,5-tetrazine with the ratio of the components M:L =1:1. The complex stability constants were determined.
机译:在包含铜(II),钴(II)和镍(II)离子(M)和3-(3,5-二甲基吡唑-1-基)-6-R-1,2,4,5的系统中形成配合物通过伏安法和分光光度法研究了-四嗪(R = 2-羟乙基氨基,哌啶子基)(L)。发现Cu(II),Co(II)和Ni(II)与1,2,4,5-四嗪的衍生物形成复杂的化合物,其组成比M:L = 1:1。确定了复数稳定性常数。

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