首页> 外文期刊>Russian Journal of General Chemistry >Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds:XLI.Solvent Effect on the Rate of 3-Methyl-3-chloro-l-butene Solvolysis.Correlation Analysis of Solvation Effects and Role of Solvent Nucleophilicity
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Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds:XLI.Solvent Effect on the Rate of 3-Methyl-3-chloro-l-butene Solvolysis.Correlation Analysis of Solvation Effects and Role of Solvent Nucleophilicity

机译:商业有机卤素化合物单分子杂化的动力学和机理:XLI。溶剂对3-甲基-3-氯-1-丁烯溶剂分解速率的影响。溶剂效应的相关性分析和亲核性的作用

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摘要

The kinetics of 3-methyl-3-chloro-l-butene solvolysis at 25 deg C in MeOH,EtOH,BuOH,i-BUOH,PentOH,2-PrOH,2-BuOH,HexOH,OctOH,t-BuOH,t-PentOH,cyclohexanol,and allyl alcohol was studied by the verdazyl method;v = k[C_5H_9Cl],SN1 + El mechanism.The reaction rate shows a satisfactory correlation with the parameter of the solvent ionizing power E_T and is independent of the solvent nucleophilicity.
机译:3-甲基-3-氯-1-丁烯在25°C下在MeOH,EtOH,BuOH,i-BUOH,PentOH,2-PrOH,2-BuOH,HexOH,OctOH,t-BuOH,t-中的动力学通过Verdazyl方法研究了戊醇,环己醇和烯丙醇; v = k [C_5H_9Cl],SN1 + El机理。反应速率与溶剂电离能E_T的参数具有令人满意的相关性,并且与溶剂的亲核性无关。

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