Kinetics and Mechanism of Monomolecular Heterolysis of Commercial Organohalogen Compounds: XXXVI.~1 Solvent Effect on the Activation Parameters of Heterolysis of 1-Methyl-1-chlorocyclohexane. Correlation Analysis of Solvation Effects in Heterolysis o

摘要

The kinetics of heterolysis of 1-methyl-1-chlorocyclohexane in six protic and eight aprotic solvents at 25-50 deg C was studied by the verdazyl method; v = k[RCl], E1 mechanism. The correlation analysis of the solvent effects on the activation free energy DELTAG~(not=), enthalpy DELTAH~(not=), and entropy DELTAS~(not=), and entropy DELTAS~(not=) of heterolysis of 1-methyl-1-chlorocyclohexane and 1-methyl-1-chlorocyclopentane was performed for the same sets of solvents.