Simulation of Electron Ionization Mass Spectra of Cycloalkyl Fluorophosphonates

摘要

The mass spectra of highly toxic cycloalkyl alkylfluorophosphonates can be divided into two components: organophosphorus and hydrocarbon. The organophosphorus component is a generalized spectral image of a taxonomic group among those forming a homologous series of cycloalkyl alkylfluorophosphonates. The hydrocarbon component is interpreted as a spectrum of the cycloolefin which is the main product of cycloalkyl alkylfluorophosphonate fragmentation. A method for simulation of the electron ionization mass spectra of these compounds is proposed.