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首页> 外文期刊>Russian Journal of General Chemistry >Unusual Structure and Reactions of l-Phenlpyrazol-5-one Annulated with 1-Methylpiperidine. A Rare Case of Auto-Alkylation
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Unusual Structure and Reactions of l-Phenlpyrazol-5-one Annulated with 1-Methylpiperidine. A Rare Case of Auto-Alkylation

机译:1-甲基哌啶环化的1-苯基吡唑-5-酮的异常结构和反应。自动烷基化的罕见情况

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摘要

The interaction of l-alkyl-3-alkoxycarbonylpyperidin-4-ones with phenylhydrazine has led to 5-alkyl-2-phenyl-3,3a,4,5,6,7-hexahydro-2//-pyrazolo-[4,3-c]pyridin-3-ones. The prepared compounds are unstable and undergo a series of uncommon transformations; their mechanisms have been suggested basing on the structural analysis of the product mixtures.
机译:1-烷基-3-烷氧基羰基哌啶丁-4-酮与苯肼的相互作用导致生成5-烷基-2-苯基-3,3a,4,5,6,7-六氢-2 /-吡唑并-[4, 3-c]吡啶-3-酮。制备的化合物不稳定,并经历一系列罕见的转化;已经根据产物混合物的结构分析提出了它们的机理。

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